Metadata: Identification_Information: Citation: Citation_Information: Originator: Amy Gartman Originator: Samantha P. Whisman Originator: James R. Hein Publication_Date: 20201103 Title: Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater Geospatial_Data_Presentation_Form: comma-delimited text Series_Information: Series_Name: data release Issue_Identification: DOI:10.5066/P9FZ16VG Publication_Information: Publication_Place: Pacific Coastal and Marine Science Center, Santa Cruz, California Publisher: U.S. Geological Survey Online_Linkage: https://doi.org/10.5066/P9FZ16VG Online_Linkage: https://www.sciencebase.gov/catalog/item/5f86121e82cebef40f14c726 Description: Abstract: This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals. These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste: ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00177, where they are also presented as Supplemental Table 1. Purpose: Data were used to determine the rate and process of sphalerite and ZnS oxidation in seawater, coupled to covellite. Time_Period_of_Content: Time_Period_Information: Range_of_Dates/Times: Beginning_Date: 20160101 Ending_Date: 20200815 Currentness_Reference: ground condition at time data were collected Status: Progress: Complete Maintenance_and_Update_Frequency: None planned Spatial_Domain: Bounding_Coordinates: West_Bounding_Coordinate: -180 East_Bounding_Coordinate: 180 North_Bounding_Coordinate: 90 South_Bounding_Coordinate: -90 Keywords: Theme: Theme_Keyword_Thesaurus: ISO 19115 Topic Category Theme_Keyword: oceans Theme_Keyword: geoscientificinformation Theme_Keyword: economy Theme: Theme_Keyword_Thesaurus: Data Categories for Marine Planning Theme_Keyword: Nonliving Resources Theme: Theme_Keyword_Thesaurus: USGS Thesaurus Theme_Keyword: chemical analysis Theme_Keyword: geochemistry Theme_Keyword: metallic mineral resources Theme: Theme_Keyword_Thesaurus: Marine Realms Information Bank (MRIB) keywords Theme_Keyword: chemical analysis Theme_Keyword: mineral resources Theme: Theme_Keyword_Thesaurus: None Theme_Keyword: U.S. Geological Survey Theme_Keyword: USGS Theme_Keyword: Coastal and Marine Hazards and Resources Program Theme_Keyword: CMHRP Theme_Keyword: Pacific Coastal and Marine Science Center Theme_Keyword: PCMSC Theme_Keyword: Marine Minerals Theme: Theme_Keyword_Thesaurus: USGS Metadata Identifier Theme_Keyword: USGS:5f86121e82cebef40f14c726 Access_Constraints: None Use_Constraints: USGS-authored or produced data and information are in the public domain from the U.S. Government and are freely redistributable with proper metadata and source attribution. Please recognize and acknowledge the U.S. Geological Survey as the originator(s) of the dataset and in products derived from these data. Point_of_Contact: Contact_Information: Contact_Organization_Primary: Contact_Organization: U.S. Geological Survey, Pacific Coastal and Marine Science Center Contact_Person: PCMSC Science Data Coordinator Contact_Address: Address_Type: mailing and physical Address: 2885 Mission Street City: Santa Cruz State_or_Province: CA Postal_Code: 95060 Contact_Voice_Telephone: 831-460-7562 Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov Native_Data_Set_Environment: This data were created using a variety of standard electrochemical geochemical techniques. Cross_Reference: Citation_Information: Originator: Amy Gartman Originator: Samantha P. Whisman Originator: James R. Hein Publication_Date: 2020 Title: Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste Other_Citation_Details: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste: ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00177 Online_Linkage: https://doi.org/10.1021/acsearthspacechem.0c00177 Cross_Reference: Citation_Information: Originator: Anna Kocyla Originator: Adam Pomorski Originator: Artur Krezel Publication_Date: 2017 Title: Molar absorption coefficients and stability constants of Zincon metal complexes for determination of metal ions and bioinorganic applications Other_Citation_Details: Kocyla, A., Pomorski, A., and Krezel, A., 2017, Molar absorption coefficients and stability constants of Zincon metal complexes for determination of metal ions and bioinorganic applications: J. Inorg. Biochem., v. 176, p. 53-65 Online_Linkage: https://doi.org/10.1016/j.jinorgbio.2017.08.006 Data_Quality_Information: Attribute_Accuracy: Attribute_Accuracy_Report: Data may be considered accurate within 10 percent. Logical_Consistency_Report: Oxygen values are always below saturation. Time progresses linearly. Completeness_Report: Data were included where measured. Positional_Accuracy: Horizontal_Positional_Accuracy: Horizontal_Positional_Accuracy_Report: no positional information in are included in the data Lineage: Process_Step: Process_Description: Results from the all lab analyses were combined into a comma-delimited text document. See accompanying manuscript for sample-processing details. Process_Date: 20200815 Process_Contact: Contact_Information: Contact_Person_Primary: Contact_Person: Amy Gartman Contact_Organization: U.S. Geological Survey Contact_Position: Research Oceanographer Contact_Address: Address_Type: mailing and physical Address: 2885 Mission St City: Santa Cruz State_or_Province: CA Postal_Code: 95060 Contact_Voice_Telephone: 831-460-7562 Contact_Electronic_Mail_Address: agartman@usgs.gov Entity_and_Attribute_Information: Detailed_Description: Entity_Type: Entity_Type_Label: Attribute table Entity_Type_Definition: Table containing attribute information associated with the dataset Entity_Type_Definition_Source: Producer defined Attribute: Attribute_Label: Trial Attribute_Definition: Number of trial Attribute_Definition_Source: producer defined Attribute_Domain_Values: Unrepresentable_Domain: trials sequentially numbered Attribute: Attribute_Label: Zn_added Attribute_Definition: concentration of zinc added at the beginning of each trial Attribute_Definition_Source: Producer defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 2.05 x 10^-4 Range_Domain_Maximum: 7.45 x 10^-3 Attribute_Units_of_Measure: moles per liter Attribute: Attribute_Label: Condition Attribute_Definition: Description of conditions under which experiment was conducted Attribute_Definition_Source: producer defined Attribute_Domain_Values: Unrepresentable_Domain: specific to each trial; see details in Gartman and others (2020) Attribute: Attribute_Label: Temperature Attribute_Definition: temperature at which experiment was conducted Attribute_Definition_Source: producer defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 22 Range_Domain_Maximum: 62 Attribute_Units_of_Measure: degrees Celsius Attribute: Attribute_Label: Time Attribute_Definition: time elapsed from onset of experiment to time of measurement Attribute_Definition_Source: producer defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 0 Range_Domain_Maximum: 123.75 Attribute_Units_of_Measure: days Attribute: Attribute_Label: Zn_measured Attribute_Definition: concentration of zinc measured; -9999 indicates no data, -8888 indicates the value was below the detection limit Attribute_Definition_Source: producer defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 1.47 x 10^-7 Range_Domain_Maximum: 1.24 x 10^-4 Attribute_Units_of_Measure: moles per liter Attribute: Attribute_Label: pH Attribute_Definition: pH of the solution; -9999 indicates no data Attribute_Definition_Source: producer defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 7.26 Range_Domain_Maximum: 8.52 Attribute_Units_of_Measure: log scale Attribute: Attribute_Label: O2 Attribute_Definition: dissolved oxygen in the solution; -9999 indicates no data Attribute_Definition_Source: Produce defined Attribute_Domain_Values: Range_Domain: Range_Domain_Minimum: 3.71 x 10^-5 Range_Domain_Maximum: 2.50 x 10^-4 Attribute_Units_of_Measure: moles per liter Overview_Description: Entity_and_Attribute_Overview: The first line of the csv file is a header line. Entity_and_Attribute_Detail_Citation: U.S. Geological Survey Distribution_Information: Distributor: Contact_Information: Contact_Organization_Primary: Contact_Organization: U.S. Geological Survey - ScienceBase Contact_Address: Address_Type: mailing and physical Address: Denver Federal Center, Building 810, Mail Stop 302 City: Denver State_or_Province: CO Postal_Code: 80225 Contact_Voice_Telephone: 1-888-275-8747 Contact_Electronic_Mail_Address: sciencebase@usgs.gov Resource_Description: These data are available in csv format contained in a single file. Distribution_Liability: Unless otherwise stated, all data, metadata and related materials are considered to satisfy the quality standards relative to the purpose for which the data were collected. Although these data and associated metadata have been reviewed for accuracy and completeness and approved for release by the U.S. Geological Survey (USGS), no warranty expressed or implied is made regarding the display or utility of the data on any other system or for general or scientific purposes, nor shall the act of distribution constitute any such warranty. Standard_Order_Process: Digital_Form: Digital_Transfer_Information: Format_Name: comma-delimited text Format_Version_Number: Microsoft Excel 16.16.17 for Mac Format_Information_Content: csv File_Decompression_Technique: No compression applied Transfer_Size: 0.035 Digital_Transfer_Option: Online_Option: Computer_Contact_Information: Network_Address: Network_Resource_Name: https://www.sciencebase.gov/catalog/file/get/5f86121e82cebef40f14c726 Network_Resource_Name: https://doi.org/10.5066/P9FZ16VG Access_Instructions: Data can be downloaded using the Network_Resource_Name links. The first link is a direct link to download the zipped file of data and metadata. The second link points to a landing page with metadata and data Fees: None. Technical_Prerequisites: These data can be viewed with any text reader software. Metadata_Reference_Information: Metadata_Date: 20201103 Metadata_Contact: Contact_Information: Contact_Organization_Primary: Contact_Organization: U.S. Geological Survey, Pacific Coastal and Marine Science Center Contact_Person: PCMSC Science Data Coordinator Contact_Address: Address_Type: mailing and physical Address: 2885 Mission Street City: Santa Cruz State_or_Province: CA Postal_Code: 95060 Contact_Voice_Telephone: 831-427-4747 Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov Metadata_Standard_Name: Content Standard for Digital Geospatial Metadata Metadata_Standard_Version: FGDC-STD-001-1998