Metal and other element partitioning in southwest Puerto Rico ultramafic soil, Rio Loco sediment, and Guanica Bay sediment

Renee K. Takesue 20220726 Metal and other element partitioning in southwest Puerto Rico ultramafic soil, Rio Loco sediment, and Guanica Bay sediment comma-delimited text data release DOI:10.5066/P9MN33MB Pacific Coastal and Marine Science Center, Santa Cruz, California U.S. Geological Survey https://doi.org/10.5066/P9MN33MB https://www.sciencebase.gov/catalog/item/614e30d0d34e0df5fb98a12f Five-stage sequential extractions were performed on ultramafic soil from Bosque Susua and Guanica Dry Forest, stream sediment from Rios Loco and Yauco, and nearshore sediment from Guanica Bay in southwest Puerto Rico. Sequential extractions showed partitioning of geologically enriched metals and other elements among five phases: 1) adsorbed and calcium-bound, 2) iron-, manganese-oxyhydroxide-bound, 3) crystalline iron-oxide-bound, 4) sulfide-bound, and 5) residual. Total element contents are also reported. Soil and sediment were collected between June 19, 2017, and March 27, 2018. Partitioning of potentially toxic metals was investigated in serpentinite other types of soils in Rio Loco and adjacent watersheds to determine potential metal mobility, bioavailability, and environmental health risk from geologically enriched metals. Additional information about the field activities from which these data were derived is available online at: https://cmgds.er.usgs.gov/fan_info.php?fan=2017-625-FA Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. 20170619 20180327 Stream and nearshore sediment were collected in June 2017. Soil was collected in January and March 2018. Complete None planned -66.92442 -66.84019 18.07070 17.95574 ISO 19115 Topic Category environment geoscientificInformation Data Categories for Marine Planning Substrate USGS Thesaurus geochemistry soil chemistry mass spectroscopy Marine Realms Information Bank (MRIB) keywords Watershed Coastal plain River Bay Soil Sediment None U.S. Geological Survey USGS Coastal and Marine Hazards and Resources Program CMHRP Pacific Coastal and Marine Science Center PCMSC USGS Metadata Identifier USGS:614e30d0d34e0df5fb98a12f Geographic Names Information System (GNIS) Island of Puerto Rico Rio Loco Rio Yauco Guanica Bay None Bosque Estatal de Susua None USGS-authored or produced data and information are in the public domain from the U.S. Government and are freely redistributable with proper metadata and source attribution. Please recognize and acknowledge the U.S. Geological Survey as the originator(s) of the dataset and in products derived from these data. U.S. Geological Survey, Pacific Coastal and Marine Science Center PCMSC Science Data Coordinator mailing and physical

2885 Mission Street

Santa Cruz CA 95060 831-427-4747 pcmsc_data@usgs.gov https://www.sciencebase.gov/catalog/file/get/614e30d0d34e0df5fb98a12f?name=SouthwestPuertoRicoExtractions_sitemap.jpg&allowOpen=true Sites in southwest Puerto Rico where metal partitioning was explored. JPEG Soil and sediment were sent for sequential extractions and total element content determinations to the Analytical Chemistry Project of the USGS Geology, Geophysics, and Geochemistry Science Center (GGGSC). GGGSC performed QA/QC checks. Geochemical data are tabulated in comma separated variable (CSV) format. Total element content and sequential extraction data are deemed acceptable if recovery is +/- 15 percent at five times the lower limit of determination and the calculated relative standard deviation of duplicate samples is no greater than 15 percent. Fifteen of twenty four determinations of the attribute Total Selenium (Se_total) and one of twenty four determinations of the attribute Total Tellurium (Te_total) did not meet these quality control criteria and were replaced with the numerical code -1111. No formal logical consistency tests were conducted. Silica and rare earth element contents were not determined in sequential extractions. Sodium was not measured in the adsorbed, calcium-bound, and iron and manganese oxyhydroxide fractions. Potassium was not measured in the sulfide-bound and residual fractions. A Garmin 78sc handheld GPS reported a horizontal accuracy of +/- 3 meters. International Atomic Energy Agency 1987 IAEA-RGU-1, Uranium Ore Certified Reference Material online International Atomic Energy Agency https://nucleus.iaea.org/sites/ReferenceMaterials/Pages/IAEA-RGU-1.aspx online document 20161020 20190812 The certification of IAEA-RGU-1 is valid indefinitely. IAEA-RGU-1 Certificate of analysis The Certificate lists the certified properties for IAEA-RGU-1, their values, and estimated uncertainties. International Atomic Energy Agency 1987 IAEA-RGTh-1, Thorium Ore Certified Reference Material online International Atomic Energy Agency https://nucleus.iaea.org/sites/ReferenceMaterials/Pages/IAEA-RGTh-1.aspx online document 20161020 20190812 The certification of IAEA-RGTh-1 is valid indefinitely. IAEA-RGTh-1 Certificate of analysis The Certificate lists the certified properties for IAEA-RGTh-1, their values, and estimated uncertainties. Ballestra, S. Gastaud, J. Lopez, J.J. Parsi, P. Vas, D. 1994 Intercomparison of radionuclide measurements on marine sediment sample IAEA-300 online International Atomic Energy Agency https://inis.iaea.org/collection/NCLCollectionStore/_Public/35/066/35066057.pdf online document 20161020 20190812 The certification of IAEA-300 is valid indefinitely. Certificate of analysis The Certificate lists the certified properties for IAEA-300, their values, and estimated uncertainties. SOIL AND SEDIMENT COLLECTION: Find-grained stream sediment was collected by hand from stream banks or stream beds June 19-21, 2017, and placed into wire-top polyethylene bags. Seabed sediment was collected using a boat-deployed Petit Ponar benthic grab sampler, and the 0-2 centimeter surface layer was subsampled into wire-top polyethylene bags. Forest soil was collected from Guanica Dry Forest on January 19, 2018, and from two sites in the Bosque Susua on March 27, 2018. A shallow trench was dug in the forest floor at each site and 2-centimeter-thick soil intervals were subsampled into wire-top polyethylene bags. Soils up to 6 centimeters deep were sampled from Guanica Dry Forest and up to 8 centimeters deep from Bosque Susua. 20180327 SEDIMENT SAMPLE PREPARATION: Soil and sediment were oven-dried at 60 degrees Celsius, disaggregated gently to avoid changing grain sizes, and dry-sieved through stainless steel sieves to obtain the less than 0.063 millimeter-diameter fine fraction for sequential extractions and analyses of total element contents. 20190808 SHORT-LIVED RADIONUCLIDE ACTIVITIES: Bulk sediment was oven-dried at 60 degrees Celsius, homogenized, and packed into 10 milliliter vials with air-tight caps. Activities of short-lived radionuclides were counted for 72 hours in a high-purity low-background germanium (HPGe) well detector at the USGS Pacific Coastal and Marine Science Center and quantified relative to certified reference materials with similar geometries and counting times. Beryllium-7 activities were counted at 477.6 kiloelectron volts (keV) and Cesium-137 activities at 661.6 keV. Unsupported Lead-210 activities were calculated by subtracting Lead-210 activities counted at 46.52 keV from the average of supported Radium-226 activities counted indirectly at 351.9 keV and 609.3 keV. Detector efficiency for Beryllium-7 was interpolated from peaks at 351.9 keV and 609.3 keV using International Atomic Energy Agency (IAEA) reference standard RGU-1. Detector efficiency for Cesium-137 was determined using IAEA Standard Reference Material 300. Detector efficiency for Lead-210 was determined using IAEA standards RGU-1 and RGTh-1. Combined uncertainties include 1-sigma counting errors, detector efficiency, and background corrections. 20190103 SEQUENTIAL EXTRACTIONS: Fine-grained (less than 0.063-mm-diameter) soil and sediment were sent to the Analytical Chemistry Project of the USGS Geology, Geophysics, and Geochemistry Science Center (GGGSC), which contracted with nationally accredited AGAT Laboratories for 5-stage sequential extractions. The five phases are operationally defined and include: 1) adsorbed and calcium-bound, 2) hydrous iron-, manganese-oxide-bound, 3) crystalline iron-oxide-bound, 4) sulfide-bound, and 5) residual. Quantification was performed by inductively coupled plasma optical emission spectroscopy (ICP-OES) for major and some minor elements and by inductively coupled plasma mass spectroscopy (ICP-MS) for some minor and all trace elements. 20191011 Jaime Azain U.S. Geological Survey, Central Mineral and Environmental Resources Science Center Research Geologist mailing

Denver Federal Center, Bldg 20

Denver CO 80225 303-236-9376 jsazain@usgs.gov TOTAL ELEMENT CONTENTS: Fine-grained (less than 0.063-mm-diameter) soil and sediment were sent to the Analytical Chemistry Project of the USGS Geology, Geophysics, and Geochemistry Science Center (GGGSC), which contracted with nationally accredited AGAT Laboratories for total element content analyses. Soil and sediment were decomposed with a four-acid digestion at low temperature or a sodium peroxide fusion at 750 degrees Celsius followed by reconstitution in nitric acid for elements hosted in acid-resistant minerals. Quantification was performed by inductively coupled plasma optical emission spectroscopy (ICP-OES) for major and some minor elements and by inductively coupled plasma mass spectroscopy (ICP-MS) for some minor and all trace elements. Total mercury was measured by cold vapor atomic absorption. 20191011 Jaime Azain U.S. Geological Survey, Central Mineral and Environmental Resources Science Center Research Geologist mailing

Denver Federal Center, Bldg 20

Denver CO 80225 303-236-9376 jsazain@usgs.gov Point Point 24 0.00001 0.00001 Decimal degrees D_WGS_1984 WGS84 6378137.0000 298.2572 Attribute table Table of data. Abbreviations: -1111, data did not meet quality control criteria described in the Attribute Accuracy Report; -9999, value was below the reporting limit given in the Attribute Definition; Blank cells indicate no measurement was made (no data). Producer defined Sample I.D. Unique laboratory identifier assigned to each sample by the GGGSC Analytical Chemistry Laboratory Producer defined Sequential sample identification numbers assigned by the GGGSC Analytical Chemistry Laboratory Field I.D. Sample identifier assigned during field collection based on location. Producer defined Unique alphanumeric sample identifiers Sample type Type of sediment sample Producer defined TER terrestrial sample collected at or landward of the shoreline Producer defined MAR marine sample collected seaward of the shoreline Producer defined Sampled feature Geomorphic feature from which the sample was collected Producer defined soil in situ forest soil Producer defined stream flowing freshwater body Producer defined seabed seafloor Producer defined Collection date Date the sample was collected, in mm/dd/yy Producer defined 06/19/17 03/27/18 mm/dd/yy 1 Latitude Latitude where the sample was collected Producer defined 17.95574 18.07070 decimal degrees 0.00001 Longitude Longitude where the sample was collected Producer defined -66.92442 -66.84019 decimal degrees 0.00001 Datum Geodetic datum coordinate system Producer defined WGS84 World Geodetic System 1984 Producer defined Drainage name Geographic area or drainage basin in which sediment was collected Producer defined Guanica Bay Guanica Bay Producer defined Rio Loco Rio Loco watershed Producer defined Yauco Rio Yauco watershed Producer defined Beryllium-7 activity Activity of Beryllium-7 corrected to the date of collection. Producer defined 0.0 0.7 disintegrations per minute per gram (dpm per g) 0.1 Beryllium-7 activity uncertainty Combined uncertainty from 1-sigma counting errors, detector efficiency, and background corrections. Producer defined 0.1 0.1 disintegrations per minute per gram (dpm per g) 0.1 Cesium-137 activity Activity of Cesium-137 corrected to the date of collection. Producer defined 0.0 0.3 disintegrations per minute per gram (dpm per g) 0.1 Cesium-137 activity uncertainty Combined uncertainty from 1-sigma counting errors, detector efficiency, and background corrections. Producer defined 0.0 0.2 disintegrations per minute per gram (dpm per g) 0.1 Unsupported Lead-210 activity Activity of Lead-210 corrected to the date of collection. Producer defined -0.2 5.1 disintegrations per minute per gram (dpm per g) 0.1 Unsupported Lead-210 activity uncertainty Combined uncertainty from 1-sigma counting errors, detector efficiency, and background corrections. Producer defined 0.1 0.2 disintegrations per minute per gram (dpm per g) 0.1 Al_total Total aluminum (Al) content determined by the sodium peroxide fusion method. Producer defined 1.18 7.73 weight percent (wt %) 0.01 Al_ads_Ca Aluminum (Al) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.01 weight percent (wt %) 0.01 Al_hydr_Fe_Mn Aluminum (Al) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.31 0.99 weight percent (wt %) 0.01 Al_FeOx Aluminum (Al) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.02 0.11 weight percent (wt %) 0.01 Al_sulf Aluminum (Al) content of the sulfide (sulf) fraction. Producer defined 0.29 0.91 weight percent (wt %) 0.01 Al_resid Aluminum (Al) content of the residual (resid) fraction. Producer defined 0.44 4.27 weight percent (wt %) 0.01 Ca_total Total calcium (Ca) content determined by the sodium peroxide fusion method. Producer defined 0.47 20.10 weight percent (wt %) 0.01 Ca_ads_Ca Calcium (Ca) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 752 179,000 milligram per kilogram (mg/kg) 1 Ca_hydr_Fe_Mn Calcium (Ca) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 803 33,800 milligram per kilogram (mg/kg) 1 Ca_FeOx Calcium (Ca) content of the crystalline iron oxide (FeOx) fraction. Producer defined 215 772 milligram per kilogram (mg/kg) 1 Ca_sulf Calcium (Ca) content of the sulfide (sulf) fraction. Producer defined 641 3,060 milligram per kilogram (mg/kg) 1 Ca_resid Calcium (Ca) content of the residual (resid) fraction. Producer defined 1,080 11,400 milligram per kilogram (mg/kg) 1 Fe_total Total iron (Fe) content determined by the sodium peroxide fusion method. Producer defined 2.9 16.6 weight percent (wt %) 0.1 Fe_ads_Ca Iron (Fe) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 5. Producer defined 6 759 milligram per kilogram (mg/kg) 1 Fe_hydr_Fe_Mn Iron (Fe) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 9,390 22,300 milligram per kilogram (mg/kg) 1 Fe_FeOx Iron (Fe) content of the crystalline iron oxide (FeOx) fraction. Producer defined 1,790 29,000 milligram per kilogram (mg/kg) 1 Fe_sulf Iron (Fe) content of the sulfide (sulf) fraction. Producer defined 7,850 61,100 milligram per kilogram (mg/kg) 1 Fe_resid Iron (Fe) content of the residual (resid) fraction. Producer defined 6,910 55,500 milligram per kilogram (mg/kg) 1 K_total Total potassium (K) content determined by the sodium peroxide fusion method. Producer defined 0.05 1.61 weight percent (wt %) 0.01 K_ads_Ca Potssium (K) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 137 2,570 milligram per kilogram (mg/kg) 1 K_hydr_Fe_Mn Potssium (K) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 77 1,200 milligram per kilogram (mg/kg) 1 K_FeOx Potssium (K) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 5. Producer defined 7 138 milligram per kilogram (mg/kg) 1 Mg_total Total magnesium (Mg) content determined by the sodium peroxide fusion method. Producer defined 1.93 12.10 weight percent (wt %) 0.01 Mg_ads_Ca Magnesium (Mg) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 1,410 9,110 milligram per kilogram (mg/kg) 1 Mg_hydr_Fe_Mn Magnesium (Mg) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 8,500 40,000 milligram per kilogram (mg/kg) 1 Mg_FeOx Magnesium (Mg) content of the crystalline iron oxide (FeOx) fraction. Producer defined 823 22,300 milligram per kilogram (mg/kg) 1 Mg_sulf Magnesium (Mg) content of the sulfide (sulf) fraction. Producer defined 3,150 30,000 milligram per kilogram (mg/kg) 1 Mg_resid Magnesium (Mg) content of the residual (resid) fraction. Producer defined 3,450 31,000 milligram per kilogram (mg/kg) 1 Na_total Total sodium (Na) content determined by the sodium peroxide fusion method. Producer defined 0.05 2.84 weight percent (wt %) 0.01 Na_FeOx Sodium (Na) content of the crystalline iron oxide (FeOx) fraction. Producer defined 23 204 milligram per kilogram (mg/kg) 1 Na_sulf Sodium (Na) content of the sulfide (sulf) fraction. Producer defined 14 104 milligram per kilogram (mg/kg) 1 Na_resid Sodium (Na) content of the residual (resid) fraction. Producer defined 402 16,300 milligram per kilogram (mg/kg) 1 P_total Total phosphorus (P) content determined by the four-acid digestion method. Producer defined 216 1,320 milligram per kilogram (mg/kg) 1 P_ads_Ca Phosphorus (P) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 6 121 milligram per kilogram (mg/kg) 1 P_hydr_Fe_Mn Phosphorus (P) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 5 924 milligram per kilogram (mg/kg) 1 P_FeOx Phosphorus (P) content of the crystalline iron oxide (FeOx) fraction. Producer defined 40 144 milligram per kilogram (mg/kg) 1 P_sulf Phosphorus (P) content of the sulfide (sulf) fraction. Producer defined 57 251 milligram per kilogram (mg/kg) 1 P_resid Phosphorus (P) content of the residual (resid) fraction. Producer defined 33 159 milligram per kilogram (mg/kg) 1 S_total Total sulfur (S) content determined by the sodium peroxide fusion method. -9999, less than the reporting limit of 0.1. Producer defined 0.1 1.7 weight percent (wt %) 0.1 S_ads_Ca Sulfur (S) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.14 0.49 weight percent (wt %) 0.01 S_hydr_Fe_Mn Sulfur (S) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.01 weight percent (wt %) 0.01 S_FeOx Sulfur (S) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 weight percent (wt %) 0.01 S_sulf Sulfur (S) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 1.13 weight percent (wt %) 0.01 S_resid Sulfur (S) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 weight percent (wt %) 0.01 Si_total Total silicon (Si) content determined by the sodium peroxide fusion method. Producer defined 9.9 25.4 weight percent (wt %) 0.1 Ti_total Total titanium (Ti) content determined by the sodium peroxide fusion method. Producer defined 0.04 0.61 weight percent (wt %) 0.01 Ti_ads_Ca Titanium (Ti) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined less than 0.005 less than 0.005 weight percent (wt %) 0.001 Ti_hydr_Fe_Mn Titanium (Ti) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined less than 0.005 less than 0.005 weight percent (wt %) 0.001 Ti_FeOx Titanium (Ti) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined less than 0.005 less than 0.005 weight percent (wt %) 0.001 Ti_sulf Titanium (Ti) content of the sulfide (sulf) fraction. Producer defined 0.011 0.122 weight percent (wt %) 0.001 Ti_resid Titanium (Ti) content of the residual (resid) fraction. Producer defined 0.026 0.466 weight percent (wt %) 0.001 Ag_total Total silver (Ag) content determined by the four-acid digestion method. -9999, less than the reporting limit of 0.01. Producer defined 0.02 0.92 milligram per kilogram (mg/kg) 0.01 Ag_ads_Ca Silver (Ag) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.002. Producer defined 0.002 0.009 milligram per kilogram (mg/kg) 0.001 Ag_hydr_Fe_Mn Silver (Ag) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.019 0.120 milligram per kilogram (mg/kg) 0.001 Ag_FeOx Silver (Ag) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.004 0.055 milligram per kilogram (mg/kg) 0.001 Ag_sulf Silver (Ag) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.002. Producer defined 0.002 0.055 milligram per kilogram (mg/kg) 0.001 Ag_resid Silver (Ag) content of the residual (resid) fraction. Producer defined 0.030 0.382 milligram per kilogram (mg/kg) 0.001 As_total Total arsenic (As) content determined by the four-acid digestion method. Producer defined 0.8 14.0 milligram per kilogram (mg/kg) 0.1 As_ads_Ca Arsenic (As) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.05 1.14 milligram per kilogram (mg/kg) 0.01 As_hydr_Fe_Mn Arsenic (As) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.06 2.85 milligram per kilogram (mg/kg) 0.01 As_FeOx Arsenic (As) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.02 0.85 milligram per kilogram (mg/kg) 0.01 As_sulf Arsenic (As) content of the sulfide (sulf) fraction. Producer defined 0.02 11.20 milligram per kilogram (mg/kg) 0.01 As_resid Arsenic (As) content of the residual (resid) fraction. Producer defined 0.13 2.05 milligram per kilogram (mg/kg) 0.01 Ba_total Total barium (Ba) content determined by the four-acid digestion method. Producer defined 41 1,320 milligram per kilogram (mg/kg) 1 Ba_ads_Ca Baruim (Ba) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 2.7 98.0 milligram per kilogram (mg/kg) 0.1 Ba_hydr_Fe_Mn Baruim (Ba) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 2.5 195.0 milligram per kilogram (mg/kg) 0.1 Ba_FeOx Baruim (Ba) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.4 11.3 milligram per kilogram (mg/kg) 0.1 Ba_sulf Baruim (Ba) content of the sulfide (sulf) fraction. Producer defined 0.8 23.2 milligram per kilogram (mg/kg) 0.1 Ba_resid Baruim (Ba) content of the residual (resid) fraction. Producer defined 12 1,090 milligram per kilogram (mg/kg) 1 Be_total Total beryllium (Be) content determined by the four-acid digestion method. Producer defined 0.11 1.44 milligram per kilogram (mg/kg) 0.01 Be_ads_Ca Beryllium (Be) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.11 milligram per kilogram (mg/kg) 0.01 Be_hydr_Fe_Mn Beryllium (Be) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.64 milligram per kilogram (mg/kg) 0.01 Be_FeOx Beryllium (Be) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.09 milligram per kilogram (mg/kg) 0.01 Be_sulf Beryllium (Be) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.06 0.16 milligram per kilogram (mg/kg) 0.01 Be_resid Beryllium (Be) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.10 0.35 milligram per kilogram (mg/kg) 0.01 Bi_total Total bismuth (Bi) content determined by the four-acid digestion method. Producer defined 0.01 0.12 milligram per kilogram (mg/kg) 0.01 Bi_ads_Ca Bismuth (Bi) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.008 0.012 milligram per kilogram (mg/kg) 0.001 Bi_hydr_Fe_Mn Bismuth (Bi) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.007 0.076 milligram per kilogram (mg/kg) 0.001 Bi_FeOx Bismuth (Bi) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.029 milligram per kilogram (mg/kg) 0.001 Bi_sulf Bismuth (Bi) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.028 milligram per kilogram (mg/kg) 0.001 Bi_resid Bismuth (Bi) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.009 0.010 milligram per kilogram (mg/kg) 0.001 Cd_total Total cadmium (Cd) content determined by the four-acid digestion method. Producer defined 0.04 0.19 milligram per kilogram (mg/kg) 0.01 Cd_ads_Ca Cadmium (Cd) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.009 0.056 milligram per kilogram (mg/kg) 0.001 Cd_hydr_Fe_Mn Cadmium (Cd) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.027 0.164 milligram per kilogram (mg/kg) 0.001 Cd_FeOx Cadmium (Cd) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.010 milligram per kilogram (mg/kg) 0.001 Cd_sulf Cadmium (Cd) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.010 milligram per kilogram (mg/kg) 0.001 Cd_resid Cadmium (Cd) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.011 milligram per kilogram (mg/kg) 0.001 Ce_total Total cerium (Ce) content determined by the sodium peroxide fusion method. Producer defined 4.4 47.6 milligram per kilogram (mg/kg) 0.1 Ce_ads_Ca Cerium (Ce) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.05 8.43 milligram per kilogram (mg/kg) 0.01 Ce_hydr_Fe_Mn Cerium (Ce) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 2.23 18.60 milligram per kilogram (mg/kg) 0.01 Ce_FeOx Cerium (Ce) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.18 2.45 milligram per kilogram (mg/kg) 0.01 Ce_sulf Cerium (Ce) content of the sulfide (sulf) fraction. Producer defined 0.34 3.17 milligram per kilogram (mg/kg) 0.01 Ce_resid Cerium (Ce) content of the residual (resid) fraction. Producer defined 0.96 7.21 milligram per kilogram (mg/kg) 0.01 Co_total Total cobalt (Co) content determined by the four-acid digestion method. Producer defined 17.7 384.0 milligram per kilogram (mg/kg) 0.1 Co_ads_Ca Cobalt (Co) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.2 7.2 milligram per kilogram (mg/kg) 0.1 Co_hydr_Fe_Mn Cobalt (Co) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 13.1 391.0 milligram per kilogram (mg/kg) 0.1 Co_FeOx Cobalt (Co) content of the crystalline iron oxide (FeOx) fraction. Producer defined 1.4 13.7 milligram per kilogram (mg/kg) 0.1 Co_sulf Cobalt (Co) content of the sulfide (sulf) fraction. Producer defined 4.1 32.8 milligram per kilogram (mg/kg) 0.1 Co_resid Cobalt (Co) content of the residual (resid) fraction. Producer defined 1.8 13.0 milligram per kilogram (mg/kg) 0.1 Cr_total Total chromium (Cr) content determined by the sodium peroxide fusion method. Producer defined 97 7,420 milligram per kilogram (mg/kg) 1 Cr_ads_Ca Chromium (Cr) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 1 7 milligram per kilogram (mg/kg) 1 Cr_hydr_Fe_Mn Chromium (Cr content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 13 616 milligram per kilogram (mg/kg) 1 Cr_FeOx Chromium (Cr) content of the crystalline iron oxide (FeOx) fraction. Producer defined 6 619 milligram per kilogram (mg/kg) 1 Cr_sulf Chromium (Cr) content of the sulfide (sulf) fraction. Producer defined 16 1,780 milligram per kilogram (mg/kg) 1 Cr_resid Chromium (Cr) content of the residual (resid) fraction. Producer defined 53 3,800 milligram per kilogram (mg/kg) 1 Cs_total Total cesium (Cs) content determined by the four-acid digestion method. Producer defined 0.25 1.60 milligram per kilogram (mg/kg) 0.01 Cs_ads_Ca Cesium (Cs) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.070 milligram per kilogram (mg/kg) 0.001 Ce_hydr_Fe_Mn Cesium (Cs) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.013 0.069 milligram per kilogram (mg/kg) 0.001 Cs_FeOx Cesium (Cs) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.009 0.061 milligram per kilogram (mg/kg) 0.001 Cs_sulf Cesium (Cs) content of the sulfide (sulf) fraction. Producer defined 0.031 0.169 milligram per kilogram (mg/kg) 0.001 Cs_resid Cesium (Cs) content of the residual (resid) fraction. Producer defined 0.113 0.944 milligram per kilogram (mg/kg) 0.001 Cu_total Total copper (Cu) content determined by the four-acid digestion method. Producer defined 16.5 109.0 milligram per kilogram (mg/kg) 0.1 Cu_ads_Ca Copper (Cu) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.126 5.120 milligram per kilogram (mg/kg) 0.001 Ce_hydr_Fe_Mn Cesium (Cs) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 5.74 39.40 milligram per kilogram (mg/kg) 0.01 Cs_FeOx Cesium (Cs) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.37 8.74 milligram per kilogram (mg/kg) 0.01 Cs_sulf Cesium (Cs) content of the sulfide (sulf) fraction. Producer defined 7.78 31.40 milligram per kilogram (mg/kg) 0.01 Cs_resid Cesium (Cs) content of the residual (resid) fraction. Producer defined 2.26 22.90 milligram per kilogram (mg/kg) 0.01 Dy_total Total dysprosium (Dy) content determined by the sodium peroxide fusion method. Producer defined 0.38 3.79 milligram per kilogram (mg/kg) 0.01 Er_total Total erbium (Er) content determined by the sodium peroxide fusion method. Producer defined 0.24 2.34 milligram per kilogram (mg/kg) 0.01 Eu_total Total europium (Eu) content determined by the sodium peroxide fusion method. Producer defined 0.08 1.47 milligram per kilogram (mg/kg) 0.01 Ga_total Total gallium (Ga) content determined by the four-acid digestion method. Producer defined 2.48 16.40 milligram per kilogram (mg/kg) 0.01 Ga_ads_Ca Gallium (Ga) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.07 milligram per kilogram (mg/kg) 0.01 Ga_hydr_Fe_Mn Gallium (Ga) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.17 1.58 milligram per kilogram (mg/kg) 0.01 Ga_FeOx Gallium (Ga) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.07 0.56 milligram per kilogram (mg/kg) 0.01 Ga_sulf Gallium (Ga) content of the sulfide (sulf) fraction. Producer defined 1.52 5.60 milligram per kilogram (mg/kg) 0.01 Ga_resid Gallium (Ga) content of the residual (resid) fraction. Producer defined 1.07 8.90 milligram per kilogram (mg/kg) 0.01 Gd_total Total gadolinium (Gd) content determined by the sodium peroxide fusion method. Producer defined 0.42 4.85 milligram per kilogram (mg/kg) 0.01 Ge_total Total germanium (Ge) content determined by the sodium peroxide fusion method. -9999, less than the reporting limit of 1. Producer defined 1 2 milligram per kilogram (mg/kg) 1 Ge_ads_Ca Germanium (Ge) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined less than 0.05 less than 0.05 milligram per kilogram (mg/kg) 0.01 Ge_hydr_Fe_Mn Germanium (Ge) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.08 milligram per kilogram (mg/kg) 0.01 Ge_FeOx Germanium (Ge) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.05. Producer defined less than 0.05 less than 0.05 milligram per kilogram (mg/kg) 0.01 Ge_sulf Germanium (Ge) content of the sulfide (sulf) fraction. Producer defined 0.10 0.50 milligram per kilogram (mg/kg) 0.01 Ge_resid Germanium (Ge) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.05. Producer defined less than 0.05 less than 0.05 milligram per kilogram (mg/kg) 0.01 Hf_total Total hafnium (Hf) content determined by the sodium peroxide fusion method. -9999, less than the reporting limit of 1. Producer defined 1 3 milligram per kilogram (mg/kg) 1 Hf_ads_Ca Hafnium (Hf) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Hf_hydr_Fe_Mn Hafnium (Hf) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of. Producer defined 0.01 0.08 milligram per kilogram (mg/kg) 0.01 Hf_FeOx Hafnium (Hf) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of. Producer defined 0.01 0.05 milligram per kilogram (mg/kg) 0.01 Hf_sulf Hafnium (Hf) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of. Producer defined 0.10 0.26 milligram per kilogram (mg/kg) 0.01 Hf_resid Hafnium (Hf) content of the residual (resid) fraction. Producer defined 0.17 2.58 milligram per kilogram (mg/kg) 0.01 Hg_total Total mercury (Hg) content determined by the cold vapor atomic absorption method. Producer defined 0.022 0.209 milligram per kilogram (mg/kg) 0.001 Hg_ads_Ca Mercury (Hg) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Hg_hydr_Fe_Mn Mercury (Hg) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 Hg_FeOx Mercury (Hg) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 Hg_sulf Mercury (Hg) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.02 0.15 milligram per kilogram (mg/kg) 0.01 Hg_resid Mercury (Hg) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Ho_total Total holmium (Ho) content determined by the sodium peroxide fusion method. Producer defined 0.08 0.75 milligram per kilogram (mg/kg) 0.01 In_total Total indium (In) content determined by the four-acid digestion method. Producer defined 0.013 0.055 milligram per kilogram (mg/kg) 0.001 In_ads_Ca Indium (In) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.018 milligram per kilogram (mg/kg) 0.001 In_hydr_Fe_Mn Indium (In) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.012 milligram per kilogram (mg/kg) 0.001 In_FeOx Indium (In) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined less than 0.005 less than 0.005 milligram per kilogram (mg/kg) 0.001 In_sulf Indium (In) content of the sulfide (sulf) fraction. Producer defined 0.023 0.066 milligram per kilogram (mg/kg) 0.001 In_resid Indium (In) content of the residual (resid) fraction. Producer defined 0.006 0.034 milligram per kilogram (mg/kg) 0.001 La_total Total lanthanum (La) content determined by the sodium peroxide fusion method. Producer defined 2.2 25.4 milligram per kilogram (mg/kg) 0.1 La_ads_Ca Lanthanum (La) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.027 3.540 milligram per kilogram (mg/kg) 0.001 La_hydr_Fe_Mn Lanthanum (La) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.91 8.51 milligram per kilogram (mg/kg) 0.01 La_FeOx Lanthanum (La) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.108 1.160 milligram per kilogram (mg/kg) 0.001 La_sulf Lanthanum (La) content of the sulfide (sulf) fraction. Producer defined 0.191 1.400 milligram per kilogram (mg/kg) 0.001 La_resid Lanthanum (La) content of the residual (resid) fraction. Producer defined 0.51 4.61 milligram per kilogram (mg/kg) 0.01 Li_total Total lithium (Li) content determined by the four-acid digestion method. Producer defined 2.0 44.5 milligram per kilogram (mg/kg) 0.1 Li_ads_Ca Lithium (Li) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 1.99 milligram per kilogram (mg/kg) 0.01 Li_hydr_Fe_Mn Lithium (Li) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.18 10.00 milligram per kilogram (mg/kg) 0.01 Li_FeOx Lithium (Li) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 3.12 milligram per kilogram (mg/kg) 0.01 Li_sulf Lithium (Li) content of the sulfide (sulf) fraction. Producer defined 0.58 7.31 milligram per kilogram (mg/kg) 0.01 Li_resid Lithium (Li) content of the residual (resid) fraction. Producer defined 1.28 16.40 milligram per kilogram (mg/kg) 0.01 Lu Total lutetium (Lu) content determined by the sodium peroxide fusion method. -9999, less than the reporting limit of 0.05. Producer defined 0.08 0.31 milligram per kilogram (mg/kg) 0.01 Mn_total Total manganese (Mn) content determined by the four-acid digestion method. Producer defined 557 3,210 milligram per kilogram (mg/kg) 1 Mn_ads_Ca Manganese (Mn) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 31 410 milligram per kilogram (mg/kg) 1 Mn_hydr_Fe_Mn Manganese (Mn) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 143 2,550 milligram per kilogram (mg/kg) 1 Mn_FeOx Manganese (Mn) content of the crystalline iron oxide (FeOx) fraction. Producer defined 16 150 milligram per kilogram (mg/kg) 1 Mn_sulf Manganese (Mn) content of the sulfide (sulf) fraction. Producer defined 33 224 milligram per kilogram (mg/kg) 1 Mn_resid Manganese (Mn) content of the residual (resid) fraction. Producer defined 46 518 milligram per kilogram (mg/kg) 1 Mo_total Total molybdenum (Mo) content determined by the four-acid digestion method. Producer defined 0.25 1.80 milligram per kilogram (mg/kg) 0.01 Mo_ads_Ca Molybdenum (Mo) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.006 0.203 milligram per kilogram (mg/kg) 0.001 Mo_hydr_Fe_Mn Molybdenum (Mo) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.016 0.298 milligram per kilogram (mg/kg) 0.001 Mo_FeOx Molybdenum (Mo) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.043 0.243 milligram per kilogram (mg/kg) 0.001 Mo_sulf Molybdenum (Mo) content of the sulfide (sulf) fraction. Producer defined 0.105 1.430 milligram per kilogram (mg/kg) 0.001 Mo_resid Molybdenum (Mo) content of the residual (resid) fraction. Producer defined 0.112 0.282 milligram per kilogram (mg/kg) 0.001 Nb_total Total niobium (Nb) content determined by the four-acid digestion method. Producer defined 0.8 15.9 milligram per kilogram (mg/kg) 0.1 Nb_ads_Ca Niobium (Nb) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 Nb_hydr_Fe_Mn Niobium (Nb) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.05 milligram per kilogram (mg/kg) 0.01 Nb_FeOx Niobium (Nb) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.06 0.48 milligram per kilogram (mg/kg) 0.01 Nb_sulf Niobium (Nb) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.02 1.10 milligram per kilogram (mg/kg) 0.01 Nb_resid Niobium (Nb) content of the residual (resid) fraction. Producer defined 0.84 15.80 milligram per kilogram (mg/kg) 0.01 Nd_total Total neodymium (Nd) content determined by the sodium peroxide fusion method. Producer defined 1.8 21.7 milligram per kilogram (mg/kg) 0.1 Ni_total Total nickel (Ni) content determined by the four-acid digestion method. Producer defined 38 4,710 milligram per kilogram (mg/kg) 1 Ni_ads_Ca Nickel (Ni) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.4 198.0 milligram per kilogram (mg/kg) 0.1 Ni_hydr_Fe_Mn Nickel (Ni) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 18 2,500 milligram per kilogram (mg/kg) 1 Ni_FeOx Nickel (Ni) content of the crystalline iron oxide (FeOx) fraction. Producer defined 4 537 milligram per kilogram (mg/kg) 1 Ni_sulf Nickel (Ni) content of the sulfide (sulf) fraction. Producer defined 9 1,030 milligram per kilogram (mg/kg) 1 Ni_resid Nickel (Ni) content of the residual (resid) fraction. Producer defined 8 690 milligram per kilogram (mg/kg) 1 Pb_total Total lead (Pb) content determined by the four-acid digestion method. Producer defined 4.0 17.1 milligram per kilogram (mg/kg) 0.1 Pb_ads_Ca Lead (Pb) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.06 6.52 milligram per kilogram (mg/kg) 0.01 Pb_hydr_Fe_Mn Lead (Pb) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 2.44 13.20 milligram per kilogram (mg/kg) 0.01 Pb_FeOx Lead (Pb) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.27 1.29 milligram per kilogram (mg/kg) 0.01 Pb_sulf Lead (Pb) content of the sulfide (sulf) fraction. Producer defined 0.28 1.91 milligram per kilogram (mg/kg) 0.01 Pb_resid Lead (Pb) content of the residual (resid) fraction. Producer defined 0.32 1.40 milligram per kilogram (mg/kg) 0.01 Pr_total Total praseodymium (Pr) content determined by the sodium peroxide fusion method. Producer defined 0.47 5.19 milligram per kilogram (mg/kg) 0.01 Rb_total Total rubidium (Rb) content determined by the four-acid digestion method. Producer defined 3.8 39.8 milligram per kilogram (mg/kg) 0.1 Rb_ads_Ca Rubidium (Rb) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.077 0.634 milligram per kilogram (mg/kg) 0.001 Rb_hydr_Fe_Mn Rubidium (Rb) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.494 3.170 milligram per kilogram (mg/kg) 0.001 Rb_FeOx Rubidium (Rb) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.111 1.790 milligram per kilogram (mg/kg) 0.001 Rb_sulf Rubidium (Rb) content of the sulfide (sulf) fraction. Producer defined 0.445 4.020 milligram per kilogram (mg/kg) 0.001 Rb_resid Rubidium (Rb) content of the residual (resid) fraction. Producer defined 2.74 35.60 milligram per kilogram (mg/kg) 0.01 Sb_total Total antimony (Sb) content determined by the four-acid digestion method. Producer defined 0.12 0.67 milligram per kilogram (mg/kg) 0.01 Sb_ads_Ca Antimony (Sb) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.001. Producer defined 0.002 0.009 milligram per kilogram (mg/kg) 0.001 Sb_hydr_Fe_Mn Antimony (Sb) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.001. Producer defined 0.001 0.026 milligram per kilogram (mg/kg) 0.001 Sb_FeOx Antimony (Sb) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.001. Producer defined 0.001 0.018 milligram per kilogram (mg/kg) 0.001 Sb_sulf Antimony (Sb) content of the sulfide (sulf) fraction. Producer defined 0.003 0.205 milligram per kilogram (mg/kg) 0.001 Sb_resid Antimony (Sb) content of the residual (resid) fraction. Producer defined 0.068 0.453 milligram per kilogram (mg/kg) 0.001 Sc_total Total scandium (Sc) content determined by the four-acid digestion method. Producer defined 9.4 33.7 milligram per kilogram (mg/kg) 0.1 Sc_ads_Ca Scandium (Sc) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.1. Producer defined 0.2 0.8 milligram per kilogram (mg/kg) 0.1 Sc_hydr_Fe_Mn Scandium (Sc) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.1. Producer defined 0.1 1.1 milligram per kilogram (mg/kg) 0.1 Sc_FeOx Scandium (Sc) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.1. Producer defined 0.1 1.7 milligram per kilogram (mg/kg) 0.1 Sc_sulf Scandium (Sc) content of the sulfide (sulf) fraction. Producer defined 3.9 16.5 milligram per kilogram (mg/kg) 0.1 Sc_resid Scandium (Sc) content of the residual (resid) fraction. Producer defined 5.1 13.0 milligram per kilogram (mg/kg) 0.1 Se_total Total selenium (Se) content determined by the four-acid digestion method. -1111, value did not meet quality control criteria described in the Attribute Accuracy Report; -9999, less than the reporting limit of 0.005. Producer defined 0.5 0.7 milligram per kilogram (mg/kg) 0.1 Se_ads_Ca Selenium (Se) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.009 0.287 milligram per kilogram (mg/kg) 0.001 Se_hydr_Fe_Mn Selenium (Se) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.038 0.197 milligram per kilogram (mg/kg) 0.001 Se_FeOx Selenium (Se) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.021 0.179 milligram per kilogram (mg/kg) 0.001 Se_sulf Selenium (Se) content of the sulfide (sulf) fraction. Producer defined 0.311 0.900 milligram per kilogram (mg/kg) 0.001 Se_resid Selenium (Se) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.063 0.438 milligram per kilogram (mg/kg) 0.001 Sm_total Total samarium (Sm) content determined by the sodium peroxide fusion method. Producer defined 0.4 4.5 milligram per kilogram (mg/kg) 0.1 Sn_total Total tin (Sn) content determined by the four-acid digestion method. -9999, less than the reporting limit of 1. Producer defined 1 12 milligram per kilogram (mg/kg) 1 Sn_ads_Ca Tin (Sn) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.007 0.415 milligram per kilogram (mg/kg) 0.001 Sn_hydr_Fe_Mn Tin (Sn) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.007 0.041 milligram per kilogram (mg/kg) 0.001 Sn_FeOx Tin (Sn) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.005 0.211 milligram per kilogram (mg/kg) 0.001 Sn_sulf Tin (Sn) content of the sulfide (sulf) fraction. Producer defined 0.213 9.090 milligram per kilogram (mg/kg) 0.001 Sn_resid Tin (Sn) content of the residual (resid) fraction. Producer defined 0.191 2.860 milligram per kilogram (mg/kg) 0.001 Sr_total Total strontium (Sr) content determined by the four-acid digestion method. Producer defined 14 2,380 milligram per kilogram (mg/kg) 1 Sr_ads_Ca Strontium (Sr) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 4.2 1,860.0 milligram per kilogram (mg/kg) 0.1 Sr_hydr_Fe_Mn Strontium (Sr) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 1.65 276.00 milligram per kilogram (mg/kg) 0.01 Sr_FeOx Strontium (Sr) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.33 5.56 milligram per kilogram (mg/kg) 0.01 Sr_sulf Strontium (Sr) content of the sulfide (sulf) fraction. Producer defined 0.31 30.90 milligram per kilogram (mg/kg) 0.01 Sr_resid Strontium (Sr) content of the residual (resid) fraction. Producer defined 6 288 milligram per kilogram (mg/kg) 1 Ta_total Total tantalum (Ta) content determined by the four-acid digestion method. -9999, less than the reporting limit of 0.05. Producer defined 0.05 1.08 milligram per kilogram (mg/kg) 0.01 Ta_ads_Ca Tantalum (Ta) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Ta_hydr_Fe_Mn Tantalum (Ta) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Ta_FeOx Tantalum (Ta) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Ta_sulf Tantalum (Ta) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.01 milligram per kilogram (mg/kg) 0.01 Ta_resid Tantalum (Ta) content of the residual (resid) fraction. Producer defined 0.06 1.21 milligram per kilogram (mg/kg) 0.01 Tb_total Total terbium (Tb) content determined by the sodium peroxide fusion method. Producer defined 0.05 0.71 milligram per kilogram (mg/kg) 0.01 Te_total Total tellurium (Te) content determined by the four-acid digestion method. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.06 milligram per kilogram (mg/kg) 0.01 Te_ads_Ca Tellurium (Te) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.01 milligram per kilogram (mg/kg) 0.01 Te_hydr_Fe_Mn Tellurium (Te) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Te_FeOx Tellurium (Te) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 Te_sulf Tellurium (Te) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.06 milligram per kilogram (mg/kg) 0.01 Te_resid Tellurium (Te) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 Th_total Total thorium (Th) content determined by the sodium peroxide fusion method. Producer defined 0.5 3.5 milligram per kilogram (mg/kg) 0.1 Th_ads_Ca Thorium (Th) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.1. Producer defined 0.1 0.1 milligram per kilogram (mg/kg) 0.1 Th_hydr_Fe_Mn Thorium (Th) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.1. Producer defined less than 0.1 less than 0.1 milligram per kilogram (mg/kg) 0.1 Th_FeOx Thorium (Th) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.1. Producer defined less than 0.1 less than 0.1 milligram per kilogram (mg/kg) 0.1 Th_sulf Thorium (Th) content of the sulfide (sulf) fraction. Producer defined 0.2 1.8 milligram per kilogram (mg/kg) 0.1 Th_resid Thorium (Th) content of the residual (resid) fraction. Producer defined 0.2 1.6 milligram per kilogram (mg/kg) 0.1 Tl_total Total thallium (Tl) content determined by the four-acid digestion method. Producer defined 0.02 0.20 milligram per kilogram (mg/kg) 0.01 Tl_ads_Ca Thallium (Tl) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.005. Producer defined less than 0.005 less than 0.005 milligram per kilogram (mg/kg) 0.001 Tl_hydr_Fe_Mn Thallium (Tl) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.005 0.051 milligram per kilogram (mg/kg) 0.001 Tl_FeOx Thallium (Tl) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.041 0.059 milligram per kilogram (mg/kg) 0.001 Tl_sulf Thallium (Tl) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.006 0.084 milligram per kilogram (mg/kg) 0.001 Tl_resid Thallium (Tl) content of the residual (resid) fraction. -9999, less than the reporting limit of 0.005. Producer defined 0.006 0.105 milligram per kilogram (mg/kg) 0.001 Tm_total Total thullium (Tm) content determined by the sodium peroxide fusion method. Producer defined 0.07 0.31 milligram per kilogram (mg/kg) 0.01 U_total Total uranium (U) content determined by the sodium peroxide fusion method. Producer defined 0.16 2.56 milligram per kilogram (mg/kg) 0.01 U_ads_Ca Uranium (U) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.024 1.350 milligram per kilogram (mg/kg) 0.001 U_hydr_Fe_Mn Uranium (U) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 0.035 0.406 milligram per kilogram (mg/kg) 0.001 U_FeOx Uranium (U) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.013 0.112 milligram per kilogram (mg/kg) 0.001 U_sulf Uranium (U) content of the sulfide (sulf) fraction. Producer defined 0.017 0.355 milligram per kilogram (mg/kg) 0.001 U_resid Uranium (U) content of the residual (resid) fraction. Producer defined 0.066 0.475 milligram per kilogram (mg/kg) 0.001 V_total Total vanadium (V) content determined by the four-acid digestion method. Producer defined 51 236 milligram per kilogram (mg/kg) 1 V_ads_Ca Vanadium (V) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.08 3.45 milligram per kilogram (mg/kg) 0.01 V_hydr_Fe_Mn Vanadium (V) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 12.1 59.2 milligram per kilogram (mg/kg) 0.1 V_FeOx Vanadium (V) content of the crystalline iron oxide (FeOx) fraction. Producer defined 2.4 29.7 milligram per kilogram (mg/kg) 0.1 V_sulf Vanadium (V) content of the sulfide (sulf) fraction. Producer defined 12.5 61.5 milligram per kilogram (mg/kg) 0.1 V_resid Vanadium (V) content of the residual (resid) fraction. Producer defined 15.0 113.0 milligram per kilogram (mg/kg) 0.1 W_total Total tungsten (W) content determined by the four-acid digestion method. -9999, less than the reporting limit of 0.1. Producer defined 0.2 0.4 milligram per kilogram (mg/kg) 0.1 W_ads_Ca Tungsten (W) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.01. Producer defined less than 0.01 less than 0.01 milligram per kilogram (mg/kg) 0.01 W_hydr_Fe_Mn Tungsten (W) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 W_FeOx Tungsten (W) content of the crystalline iron oxide (FeOx) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.02 milligram per kilogram (mg/kg) 0.01 W_sulf Tungsten (W) content of the sulfide (sulf) fraction. -9999, less than the reporting limit of 0.01. Producer defined 0.01 0.19 milligram per kilogram (mg/kg) 0.01 W_resid Tungsten (W) content of the residual (resid) fraction. Producer defined 0.04 0.39 milligram per kilogram (mg/kg) 0.01 Y_total Total yttrium (Y) content determined by the sodium peroxide fusion method. Producer defined 2.1 19.7 milligram per kilogram (mg/kg) 0.1 Y_ads_Ca Yttrium (Y) content of the adsorbed (ads) and calcium (Ca)-bound fraction. Producer defined 0.05 4.58 milligram per kilogram (mg/kg) 0.01 Y_hydr_Fe_Mn Yttrium (Y) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 1.04 9.00 milligram per kilogram (mg/kg) 0.01 Y_FeOx Yttrium (Y) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.10 1.06 milligram per kilogram (mg/kg) 0.01 Y_sulf Yttrium (Y) content of the sulfide (sulf) fraction. Producer defined 0.31 2.01 milligram per kilogram (mg/kg) 0.01 Y_resid Yttrium (Y) content of the residual (resid) fraction. Producer defined 0.52 3.92 milligram per kilogram (mg/kg) 0.01 Yb_total Total ytterbium (Yb) content determined by the sodium peroxide fusion method. Producer defined 0.2 2.1 milligram per kilogram (mg/kg) 0.1 Zn_total Total zinc (Zn) content determined by the four-acid digestion method. Producer defined 35.4 118.0 milligram per kilogram (mg/kg) 0.1 Zn_ads_Ca Zinc (Zn) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.1. Producer defined 0.3 6.1 milligram per kilogram (mg/kg) 0.1 Zn_hydr_Fe_Mn Zinc (Zn) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. Producer defined 17.5 63.2 milligram per kilogram (mg/kg) 0.1 Zn_FeOx Zinc (Zn) content of the crystalline iron oxide (FeOx) fraction. Producer defined 2.0 10.0 milligram per kilogram (mg/kg) 0.1 Zn_sulf Zinc (Zn) content of the sulfide (sulf) fraction. Producer defined 4.1 20.8 milligram per kilogram (mg/kg) 0.1 Zn_resid Zinc (Zn) content of the residual (resid) fraction. Producer defined 8.7 72.5 milligram per kilogram (mg/kg) 0.1 Zr_total Total zirconium (Zr) content determined by the sodium peroxide fusion method. Producer defined 8.0 127.0 milligram per kilogram (mg/kg) 0.1 Zn_ads_Ca Zinc (Zn) content of the adsorbed (ads) and calcium (Ca)-bound fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.05 0.20 milligram per kilogram (mg/kg) 0.01 Zn_hydr_Fe_Mn Zinc (Zn) content of the hydrous iron (Fe) and manganese (Mn) oxide fraction. -9999, less than the reporting limit of 0.05. Producer defined 0.06 2.60 milligram per kilogram (mg/kg) 0.01 Zn_FeOx Zinc (Zn) content of the crystalline iron oxide (FeOx) fraction. Producer defined 0.09 2.90 milligram per kilogram (mg/kg) 0.01 Zn_sulf Zinc (Zn) content of the sulfide (sulf) fraction. Producer defined 0.16 8.47 milligram per kilogram (mg/kg) 0.01 Zn_resid Zinc (Zn) content of the residual (resid) fraction. Producer defined 6.8 138.0 milligram per kilogram (mg/kg) 0.1 The first line of the csv file is a header line. U.S. Geological Survey U.S. Geological Survey - ScienceBase mailing and physical

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Denver CO 80225 1-888-275-8747 sciencebase@usgs.gov These data are available in csv format (SouthwestPuertoRicoSedimentExtractions_data.csv) contained in a single zip file which also includes CSDGM FGDC compliant metadata. Unless otherwise stated, all data, metadata and related materials are considered to satisfy the quality standards relative to the purpose for which the data were collected. Although these data and associated metadata have been reviewed for accuracy and completeness and approved for release by the U.S. Geological Survey (USGS), no warranty expressed or implied is made regarding the display or utility of the data on any other system or for general or scientific purposes, nor shall the act of distribution constitute any such warranty. comma-delimited text Zip file contains the csv table and the associated metadata. No compression applied. 0.04 https://www.sciencebase.gov/catalog/item/614e30d0d34e0df5fb98a12f https://doi.org/10.5066/P9MN33MB Data can be downloaded using the Network_Resource_Name links. The first link is a direct link to download the zipped file of data and metadata. The second link points to a landing page with metadata and data None. These data can be viewed with any text reader. 20220726 U.S. Geological Survey, Pacific Coastal and Marine Science Center PCMSC Science Data Coordinator mailing and physical

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