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Comparison of methane concentration and stable carbon isotope data for natural samples analyzed by discrete sample introduction module - cavity ring down spectroscopy (DSIM-CRDS) and traditional methods
A discrete sample introduction module (DSIM) was developed and interfaced to a cavity ring-down spectrometer to enable measurements of methane and CO2 concentrations and 13C values with a commercially available cavity ring-down spectrometer (CRDS). The DSIM-CRDS system permits the analysis of limited volume (5 - 100-ml) samples ranging six orders-of-magnitude from 100% analyte to the lower limit of instrument detection (2 ppm). We demonstrate system performance for methane by comparing concentrations and ... |
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Data and calculations to support the study of the sea-air flux of methane and carbon dioxide on the West Spitsbergen margin in June 2014
A critical question for assessing global greenhouse gas budgets is how much of the methane that escapes from seafloor cold seep sites to the overlying water column eventually crosses the sea-air interface and reaches the atmosphere. The issue is particularly important in Arctic Ocean waters since rapid warming there increases the likelihood that gas hydrate--an ice-like form of methane and water stable at particular pressure and temperature conditions within marine sediments--will break down and release its ... |
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Temporal hydrologic and chemical records from the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula, from January 2015 to January 2016
Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to investigate how regional meteorology and hydrology control methane dynamics in karst subterranean estuaries. Three field trips were carried out in January 2015, June 2015, and January 2016 to obtain year-long high-resolution temporal records of water chemistry and environmental parameters below and above the surface at a site (Cenote Bang) within the Ox Bel Ha cave network. These efforts resulted in ... |
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Vertical chemical profiles collected across haloclines in the water column of the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula in January 2015 and January 2016
Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to test the hypothesis that chemoclines associated with salinity gradients (haloclines) within the flooded cave networks of the karst subterranean estuary are sites of methane oxidation. Two field trips were carried out to the fully-submerged cave system located 6.6 km inland from the coastline in January 2015 and January 2016. Vertical chemical profiles across the water column haloclines were obtained using ... |
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