Geochemical analysis of authigenic carbonates and chemosynthetic mussels at Atlantic Margin seeps (ver. 2.0, March 2019)

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Frequently anticipated questions:


What does this data set describe?

Title:
Geochemical analysis of authigenic carbonates and chemosynthetic mussels at Atlantic Margin seeps (ver. 2.0, March 2019)
Abstract:
Isotopic analyses of authigenic carbonates and methanotrophic deep-sea mussels, Bathymodiolus sp., was performed on samples collected from seep fields in the Baltimore and Norfolk Canyons on the north Atlantic margin. Samples were collected using remotely operated underwater vehicles (ROVs) during three different research cruises in 2012, 2013, and 2015. Analyses were performed by several different laboratories, and the results are presented in spreadsheet format.
Supplemental_Information:
Additional information about the field activities during which the 2012 and 2013 samples were collected is available online at: http://cmgds.marine.usgs.gov/fan_info.php?fan=F0112MC http://cmgds.marine.usgs.gov/fan_info.php?fan=B0413MC Samples from 2015 were collected by Dr. Cindy Van Dover from Duke University (http://oceanography.ml.duke.edu/vandover/people/about/) during one of their research cruises, and as such, no USGS field activity information exists. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
  1. How might this data set be cited?
    Prouty, Nancy G., 2016, Geochemical analysis of authigenic carbonates and chemosynthetic mussels at Atlantic Margin seeps (ver. 2.0, March 2019): data release DOI:10.5066/F77942SJ, U.S. Geological Survey, Pacific Coastal and Marine Science Center, Santa Cruz, California.

    Online Links:

  2. What geographic area does the data set cover?
    West_Bounding_Coordinate: -74.5811
    East_Bounding_Coordinate: -73.7412
    North_Bounding_Coordinate: 38.0977
    South_Bounding_Coordinate: 36.8654
  3. What does it look like?
  4. Does the data set describe conditions during a particular time period?
    Beginning_Date: 25-Aug-2012
    Ending_Date: 21-Jul-2015
    Currentness_Reference:
    ground condition at the time the samples were collected
  5. What is the general form of this data set?
    Geospatial_Data_Presentation_Form: tabular data in .xlsx format
  6. How does the data set represent geographic features?
    1. How are geographic features stored in the data set?
      This is a Point data set. It contains the following vector data types (SDTS terminology):
      • point (254)
    2. What coordinate system is used to represent geographic features?
      Horizontal positions are specified in geographic coordinates, that is, latitude and longitude. Latitudes are given to the nearest 0.0001. Longitudes are given to the nearest 0.0001. Latitude and longitude values are specified in Decimal degrees. The horizontal datum used is D_WGS_198.
      The ellipsoid used is WGS_1984.
      The semi-major axis of the ellipsoid used is 6378137.000000.
      The flattening of the ellipsoid used is 1/298.257224.
  7. How does the data set describe geographic features?
    MDAC_Geochemistry_v.2.0.xlsx
    Table containing geochemical analyses of authigenic carbonates, sediment, water and mussels. (Source: producer defined)
    Sample ID
    The unique sample identification of a particular sample (Source: producer defined) The Sample ID contains the dive number and either a number or description of the sample in a collection series.
    Sample Type
    Explains the sample type or sample material matrix (Source: producer defined)
    ValueDefinition
    authigenic carbonate-groundmassmatrix portion of the authigenic carbonate.
    authigenic carbonate-cementprecipitate portion of the authigenic carbonate.
    shell in authigenic carbonateintact shell fragments embedded into the authigenic carbonate matrix.
    sedimentgeologic solid fragmented material, such as silt, sand, gravel.
    mussel carbonate shell (collected alive)carbonate material from mussel shells with living mussel.
    mussel carbonate shell (collected dead)carbonate material from mussel shells without living mussel.
    mussel carbonate shell (unknown)carbonate material from mussel shells but not known whether collected from living mussel.
    mussel periostracumthin, organic-rich outer layer of mussel shell.
    seawaterfiltered seawater collected from Niskin bottle.
    mussel gillgill tissue from mussel specimen
    carbonate mussel shell (collected dead) 10% HClcarbonate material from mussel shells without living mussel and pretreated with 10% hydrochloric acid.
    detritussediment analyzed to quantify the non-authigenic U and Th.
    Location
    Lists whether the sample was collected from either Baltimore Canyon or Norfolk Canyon (Source: producer defined)
    ValueDefinition
    Baltimore CanyonName of canyon where sample was collected
    Norfolk CanyonName of canyon where sample was collected
    Station Number
    Station number listed as vessel-year-number. Vessel abbreviations are as follows: RB=R/V Ron Brown; NF=R/V Nancy Foster; AT=R/V Atlantis. Year is designated with two digits (for example 03=2003; 14=2014). Number is a sequential number assigned by the vessel. Gaps in sequential numbers are common, as not all stations had samples collected or analyzed. Vessel designation AT, from the R/V Atlantis also includes the AT cruise number 29. (Source: producer defined) Station number listed as vessel-year-station number.
    Depth (m)
    Identifies either the depth range in meters or the exact depth in meters. Range is given as a function of the remotely operated underwater vehicle (ROV) dive range when it was uncertain within the dive when a specific specimen was collected and placed in the ROV sled. (Source: producer defined)
    Range of values
    Minimum:364
    Maximum:1617
    Units:meters
    Resolution:1
    Date of Collection
    Calendar date (month/day/year) when sample was collected in the field (Source: producer defined)
    Range of values
    Minimum:8/25/12
    Maximum:7/21/15
    Units:month/day/year
    Latitude
    Latitude (Source: based on ship and ROV navigation systems)
    Range of values
    Minimum:36.8654
    Maximum:38.0977
    Units:decimal degrees
    Resolution:0.0001
    Longitude
    Longitude (Source: based on ship and ROV navigation systems)
    Range of values
    Minimum:-74.5811
    Maximum:-73.7412
    Units:decimal degrees
    Resolution:0.0001
    Calcium Carbonate
    percent calcium carbonate (Source: Mineral percentages were determined by multiplying unique peak intensities for each mineral in a sample by relative intensity factors. Empty cells in the spreadsheet are common, as calcium carbonate was not calculated for every sample.)
    Range of values
    Minimum:3.30
    Maximum:97.20
    Units:percent
    Resolution:0.01
    delta-C-13
    delta-C-13 is a measure of the ratio of stable isotopes Carbon-13:Carbon-12, reported in parts per thousand (per mil). Empty cells in the spreadsheet are common, as 13C:12C was not calculated for every sample. (Source: standard reporting value in isotope chemistry)
    Range of values
    Minimum:-70.66
    Maximum:0.90
    Units:parts per thousand (per mil)
    Resolution:0.01
    delta-O-18
    delta-O-18 is a measure of the ratio of stable isotopes Oxygen-18:Oxygen-16, reported in parts per thousand (per mil). Empty cells in the spreadsheet are common, as 18O:16O was not calculated for every sample. (Source: standard reporting value in isotope chemistry)
    Range of values
    Minimum:0.34
    Maximum:5.13
    Units:parts per thousand (per mil)
    Resolution:0.01
    87Sr:86Sr
    a measure of the ratio of isotopes Strontium-87:Strontium-86. Empty cells in the spreadsheet are common, as 87Sr:86Sr was not calculated for every sample. (Source: standard reporting value in isotope chemistry)
    Range of values
    Minimum:0.70915
    Maximum:0.70924
    Resolution:0.00001
    delta-S-34
    a measure of the ratio of stable isotopes Sulfur-34:Sulfur-32, reported in parts per thousand (per mil). Empty cells in the spreadsheet are common, as 34S:32S was not calculated for every sample. (Source: standard reporting value in isotope chemistry)
    Range of values
    Minimum:-4.07
    Maximum:22.65
    Units:parts per thousand (per mil)
    Resolution:0.01
    Delta-C-14
    The relative difference between the absolute international standard (base year 1950) and sample activity corrected for age and delta-Carbon-13. Empty cells in the spreadsheet are common, as Delta-Carbon-14 was not calculated for every sample. (Source: defined in Stuiver and Polach (1977))
    Range of values
    Minimum:-959
    Maximum:-24
    Units:parts per thousand (per mil)
    Resolution:1
    Uranium
    concentration of Uranium in sample in parts per million (ppm). Empty cells in the spreadsheet are common, as Uranium concentration was not calculated for every sample. (Source: standard value in analytical chemistry)
    Range of values
    Minimum:1.1181
    Maximum:4.5917
    Units:parts per million (ppm)
    Resolution:0.0001
    232Th
    Definition: concentration of Thorium-232 in sample in parts per million (ppm). Empty cells in the spreadsheet are common, as concentration of 232Th was not calculated for every sample. (Source: standard value in isotope chemistry)
    Range of values
    Minimum:0.0650
    Maximum:18.0806
    Units:parts per billion (ppb)
    Resolution:0.0001
    230Th:232Th AR
    Thorium-230:Thorium-232 Activity Ratio. Activity ratios corrected for hydride formation, tailing, fractionation, SEM-Faraday yield, and tracer isotopic composition. Empty cells in the spreadsheet are common, as 230Th:232Th AR was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.6802
    Maximum:8.5854
    Resolution:0.0001
    232Th:238U AR
    Thorium-232:Uranium-238 Activity Ratio. Activity ratios corrected for hydride formation, tailing, fractionation, SEM-Faraday yield, and tracer isotopic composition. Empty cells in the spreadsheet are common, as 232Th:238U AR was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.0062
    Maximum:2.1560
    Resolution:0.0001
    232Th:238U AR (error)
    Thorium-232:Uranium-238 Activity Ratio error reported as 2 sigma composition. Empty cells in the spreadsheet are common, as 232Th:238U AR (error) was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.0487
    Maximum:0.5451
    Resolution:0.0001
    230Th:238U AR
    Thorium-230:Uranium-238 Activity Ratio. Activity ratios corrected for hydride formation, tailing, fractionation, SEM-Faraday yield, and tracer isotopic composition. Empty cells in the spreadsheet are common, as 230Th:238U AR was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.0240
    Maximum:2.0674
    Resolution:0.0001
    230Th:238U AR (error)
    Thorium-230:Uranium-238 Activity Ratio error reported as 2 sigma composition. Empty cells in the spreadsheet are common, as 230Th:238U AR (error) was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.24483
    Maximum:1.00785
    Resolution:0.00001
    234U:238U AR
    Uranium-234:Uranium-238 Activity Ratio. Activity ratios corrected for hydride formation, tailing, fractionation, SEM-Faraday yield, and tracer isotopic composition. Empty cells in the spreadsheet are common, as 234U:238U AR was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.9887
    Maximum:1.1447
    Resolution:0.0001
    234U:238U AR (error)
    Uranium-234:Uranium-238 Activity Ratio error reported as 2 sigma composition. Empty cells in the spreadsheet are common, as 234U:238U AR (error) was not calculated for every sample. (Source: defined in Jaffey and others, 1971)
    Range of values
    Minimum:0.1051
    Maximum:0.1543
    Resolution:0.0001
    230Th:238U AR corrected
    Corrected using average measured detrital Uranium and Thorium isotopic compositions for the Norfolk Canyon [(232Th:238U) = 1.38, (230Th:238U) = 2.05 and (234U:238U) = 0.99, n=3)] and Baltimore Canyon [(232Th:238U) = 1.39, (230Th:238U) = 1.32 and (234U:238U) = 1.00, n=3)] sites with all uncertainties set at +/- 25 percent. Empty cells in the spreadsheet are common, as 230Th:238U AR corrected was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:0.0122
    Maximum:0.1572
    Resolution:0.0001
    230Th:238U AR corrected (error)
    Corrected using average measured detrital Uranium and Thorium isotopic error reported as 2-sigma composition. Empty cells in the spreadsheet are common, as 230Th:238U AR corrected (error) was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:1.7780
    Maximum:6.8709
    Resolution:0.0001
    234U:238U AR corrected
    Corrected using average measured detrital Uranium and Thorium isotopic compositions for the Norfolk Canyon [(232Th:238U) = 1.38, (230Th:238U) = 2.05 and (234U:238U) = 0.99, n=3)] and Baltimore Canyon [(232Th:238U) = 1.39, (230Th:238U) = 1.32 and (234U:238U) = 1.00, n=3)] sites with all uncertainties set at +/- 25 percent. Empty cells in the spreadsheet are common, as 234U:238U AR corrected was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:1.1407
    Maximum:1.1461
    Resolution:0.0001
    234U:238U AR corrected (error)
    Corrected using average measured detrital Uranium and Thorium isotopic error reported as 2-sigma composition. Empty cells in the spreadsheet are common, as 234U:238U AR corrected (error) was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:0.1137
    Maximum:0.1780
    Resolution:0.0001
    Rho 08-48
    Rho 08-48 is the correlation coefficient between the 230Th:238U and 234U:238U activity ratios. Empty cells in the spreadsheet are common, as Rho 08-48 was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:-0.6879
    Maximum:-0.0044
    Resolution:0.0001
    Age (ka)
    Uranium-Thorium derived age in thousands of years. Empty cells in the spreadsheet are common, as Age (ka) was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:1.17
    Maximum:16.09
    Units:thousands of years
    Resolution:0.01
    Age error (ka)
    Uranium-Thorium derived age error. Empty cells in the spreadsheet are common, as Age error (ka) was not calculated for every sample. (Source: produced defined)
    Range of values
    Minimum:0.03
    Maximum:1.21
    Units:thousands of years
    Resolution:0.01
    Entity_and_Attribute_Overview:
    Entity and attribute information provided here describes the tabular data in the data release spreadsheet, MDAC_Geochemistry.xlsx.
    Entity_and_Attribute_Detail_Citation: U.S. Geological Survey, Nancy G. Prouty

Who produced the data set?

  1. Who are the originators of the data set? (may include formal authors, digital compilers, and editors)
    • Nancy G. Prouty
  2. Who also contributed to the data set?
    Diana Sahy, Carolyn Ruppel, Brendan Roark, Dan Condon, and Amanda Demopoulos
  3. To whom should users address questions about the data?
    U.S. Geological Survey, Pacific Coastal and Marine Science Center
    Attn: PCMSC Science Data Coordinator
    2885 Mission Street
    Santa Cruz, CA

    831-427-4747 (voice)
    pcmsc_data@usgs.gov

Why was the data set created?

These samples were collected and analyzed as part of an effort to determine the origin and age of methane seeps along the north Atlantic margin, within an area of newly discovered venting.

How was the data set created?

  1. From what previous works were the data drawn?
    87Sr:86Sr (source 1 of 5)
    U.S. Geological Survey Isotope Lab, Menlo Park CA, 2014, strontium isotope ratios.

    Type_of_Source_Media: lab sample
    Source_Contribution:
    The isotopic composition was measured on a Finnigan MAT 261 multi-collector mass spectrometer using a static-collection mode.
    U-Th dates (source 2 of 5)
    NERC Isotope Geosciences Laboratory, British Geological Survey, http://www.bgs.ac.uk/sciencefacilities/igfs/home.html, 2016, Uranium-Thorium dating.

    Type_of_Source_Media: lab sample
    Source_Contribution:
    Samples were processed via total dissolution techniques, with isotope ratios measured on a Thermo Neptune Plus multi-collector ICP-MS, relative to a mixed 229Th-236U tracer calibrated against gravimetric solutions of CRM 112a U and Ames laboratory high purity Th.
    Delta-C-14 dates (source 3 of 5)
    Keck Carbon Cycle AMS laboratory at UC Irvine; http://www.ess.uci.edu/researchgrp/ams/home, 2014, radiocarbon dating.

    Type_of_Source_Media: lab sample
    Source_Contribution:
    Radiocarbon (Delta-C-14) analysis was performed on subsamples of authigenic carbonates and mussel shells collected from dead and live mussel specimens.
    mineralogy composition (source 4 of 5)
    USGS Pacific Coastal and Marine Science Center, 2014, mineralogy.

    Type_of_Source_Media: lab sample
    Source_Contribution:
    Sample mineralogy was determined microscopically in thin sections, and by X-ray diffraction (XRD) using a Philips XRD with graphite monochromator at 40 kV and 45 mA.
    stable carbon and oxygen isotope analyses (source 5 of 5)
    Stable Isotope Geoscience Facility at Texas A&M University, College Station; http://geosciences.tamu.edu/facilities/stable-isotope-geosciences-facility/sigf-about/index.php, 2014, delta-C-13 and delta-O-18.

    Type_of_Source_Media: lab sample
    Source_Contribution:
    Data were generated from a Thermo-Finnigan MAT 253 with a Kiel IV Automated Carbonate Prep Device.
  2. How were the data generated, processed, and modified?
    Date: 29-Jun-2016 (process 1 of 6)
    Results from labs listed above were combined into an Excel spreadsheet (MDAC_Geochemistry.xlsx) for this data release. Data sources used in this process:
    • All source contributions were used for this data compilation.
    Date: 26-Mar-2019 (process 2 of 6)
    Latitude and longitude positions, and accompanying depth information, were found to be incorrect in original data and have been corrected, resulting in version 2 of this data release. Metadata file was updated to include versioning information for these corrections. Person who carried out this activity:
    Nancy Prouty
    U.S. Geological Survey, Pacific Coastal and Marine Science Center
    2885 Mission Street
    Santa Cruz, CA

    831-460-7526 (voice)
    nprouty@usgs.gov
    Date: 27-Mar-2019 (process 3 of 6)
    Metadata file was brought up to current PCMSC standards, including moving the information about the accompanying journal article from the Larger Works section to the Cross_Reference section, standardizing Cross_Reference citatons, and updating Point_of_Contact and Metadata_Contact information. No data were changed. Person who carried out this activity:
    Susan Cochran
    U.S. Geological Survey, Pacific Coastal and Marine Science Center
    2885 Mission Street
    Santa Cruz, CA

    831-460-7545 (voice)
    scochran@usgs.gov
    Date: 20-Jun-2019 (process 4 of 6)
    Edits were made to standardize a few of the "None" keywords. Person who carried out this activity:
    Susan A Cochran
    U.S. Geological Survey, Pacific Coastal and Marine Science Center
    2885 Mission St.
    Santa Cruz, CA
    United States

    831-460-7545 (voice)
    scochran@usgs.gov
    Date: 19-Oct-2020 (process 5 of 6)
    Edited metadata to add keywords section with USGS persistent identifier as theme keyword. No data were changed. Person who carried out this activity:
    U.S. Geological Survey
    Attn: VeeAnn A. Cross
    Marine Geologist
    384 Woods Hole Road
    Woods Hole, MA

    508-548-8700 x2251 (voice)
    508-457-2310 (FAX)
    vatnipp@usgs.gov
    Date: 13-Oct-2021 (process 6 of 6)
    Performed minor edits to the metadata to correct typos. No data were changed Person who carried out this activity:
    U.S. Geological Survey
    Attn: Susan A. Cochran
    Geologist
    2885 Mission Street
    Santa Cruz, CA

    831-460-7545 (voice)
    scochran@usgs.gov
  3. What similar or related data should the user be aware of?
    Prouty, Nancy G., Sahy, Diana, Ruppel, Carolyn D., Roark, E. Brendan, Condon, Dan, Brook, Sandra, Ross, Steve W., and Demopoulos, Amanda W.J., 2016, Insights into methane dynamics from analysis of authigenic carbonates and chemosynthetic mussels at newly-discovered Atlantic Margin seeps.

    Online Links:

    Other_Citation_Details:
    Prouty, N.G., Sahy, D., Ruppel, C.D., Roark, E.B., Condon, D., Brook, S., Ross, S.W., and Demopoulos, A.W.J., 2016, Insights into methane dynamics from analysis of authigenic carbonates and chemosynthetic mussels at newly-discovered Atlantic Margin seeps: Earth and Planetary Science Letters, v. 449, p. 332-344
    Stuiver, M., and Polach, H.A., 1977, Discussion reporting of 14C data.

    Other_Citation_Details:
    Stuiver, M., and Polach, H.A., 1977, Discussion reporting of 14C data: Radiocarbon, v. 19, p. 355-363
    Fisher, C.R., and Childress, J.J., 1992, Organic carbon transfer from methanotrophic symbionts to the host hydrocarbon-seep mussel.

    Other_Citation_Details:
    Fisher, C.R., and Childress, J.J., 1992, Organic carbon transfer from methanotrophic symbionts to the host hydrocarbon-seep mussel: Symbiosis, v. 12, p. 221-235
    Jaffey, A.H., Flynn, K.F., Glendenin, L.E., Bentley, W.C., and Essling, A.M., 1971, Precision measurement of half-lives and specific activities of 235U and 238U.

    Online Links:

    Other_Citation_Details:
    Jaffey, A.H., Flynn, K.F., Glendenin, L.E., Bentley, W.C., and Essling, A.M., 1971, Precision measurement of half-lives and specific activities of 235U and 238U: Physical Review C, v. 4, p. 1889-1905

How reliable are the data; what problems remain in the data set?

  1. How well have the observations been checked?
    All geochemistry data were calibrated against known standards.
  2. How accurate are the geographic locations?
    A formal accuracy assessment of the horizontal positional information in the data set has not been conducted.
  3. How accurate are the heights or depths?
    A formal accuracy assessment of the vertical positional information in the data set has not been conducted.
  4. Where are the gaps in the data? What is missing?
    Dataset is considered complete for the information presented, as described in the abstract. Users are advised to read the rest of the metadata record carefully for additional details.
  5. How consistent are the relationships among the observations, including topology?
    No formal logical accuracy tests were conducted.

How can someone get a copy of the data set?

Are there legal restrictions on access or use of the data?
Access_Constraints: None
Use_Constraints:
USGS-authored or produced data and information are in the public domain. Acknowledge the U.S. Geological Survey, National Oceanic and Atmospheric Administration (NOAA), and Bureau of Ocean Energy Management (BOEM) in products derived from these data. Share data products developed using these data with the U.S. Geological Survey.
  1. Who distributes the data set? (Distributor 1 of 1)
    U.S. Geological Survey - ScienceBase
    Denver Federal Center, Building 810, Mail Stop 302
    Denver, CO

    1-888-275-8747 (voice)
    sciencebase@usgs.gov
  2. What's the catalog number I need to order this data set? These data are available in Excel format contained in a single file.
  3. What legal disclaimers am I supposed to read?
    Unless otherwise stated, all data, metadata and related materials are considered to satisfy the quality standards relative to the purpose for which the data were collected. Although these data and associated metadata have been reviewed for accuracy and completeness and approved for release by the U.S. Geological Survey (USGS), no warranty expressed or implied is made regarding the display or utility of the data on any other system or for general or scientific purposes, nor shall the act of distribution constitute any such warranty.
  4. How can I download or order the data?

Who wrote the metadata?

Dates:
Last modified: 13-Oct-2021
Metadata author:
U.S. Geological Survey, Pacific Coastal and Marine Science Center
Attn: PCMSC Science Data Coordinator
2885 Mission Street
Santa Cruz, CA

831-427-4747 (voice)
pcmsc_data@usgs.gov
Metadata standard:
Content Standard for Digital Geospatial Metadata (FGDC-STD-001-1998)

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