Sediment core pore fluid chemistry measurements collected along the Cascadia margin for the FK190612 expedition in June 2019.

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Metadata:

Identification_Information:
Citation:
Citation_Information:
Originator: Nancy G. Prouty
Originator: Miranda Baker
Publication_Date: 20241121
Title:
Sediment core pore fluid chemistry measurements collected along the Cascadia margin for the FK190612 expedition in June 2019.
Geospatial_Data_Presentation_Form: comma-separated text
Series_Information:
Series_Name: data release
Issue_Identification: DOI: 10.5066/P1VR2IYU
Publication_Information:
Publication_Place:
Pacific Coastal and Marine Science Center, Santa Cruz, California
Publisher: U.S. Geological Survey
Online_Linkage: https://doi.org/10.5066/P1VR2IYU
Online_Linkage: Larger_Work_Citation:
Citation_Information:
Originator: Nancy G. Prouty
Originator: Miranda Baker
Originator: Pamela L. Campbell
Publication_Date: 2024
Title:
Geochemical analysis of authigenic carbonates, water column, and pore fluid measurements collected on the FK190612 research expedition in the north Pacific Ocean along the Cascadia margin in June 2019.
Series_Information:
Series_Name: data release
Issue_Identification: DOI: 10.5066/P1VR2IYU
Publication_Information:
Publication_Place: Pacific Coastal and Marine Science Center, Santa Cruz, CA
Publisher: U.S. Geological Survey
Other_Citation_Details:
Suggested Citation: Prouty, N.G., Baker, M.C., and Campbell, P.L., 2024, Geochemical analysis of authigenic carbonates, water column, and pore fluids measurements collected on the FK190612 research expedition in the north Pacific Ocean along the Cascadia margin in June 2019: U.S. Geological Survey data release, https://doi.org/10.5066/P1VR2IYU
Online_Linkage: https://doi.org/10.5066/P1VR2IYU
Online_Linkage:
Description:
Abstract:
Geochemical analysis of sediment core pore fluids collected from seep fields on the FK190612 research expedition in the north Pacific Ocean along the Cascadia margin in June 2019. Samples were collected to deconvolve the different processes impacting the fluid chemistry, including hydrate dissociation and clay mineral dehydration during the smectite-illite transformation that releases inter-layer water.
Purpose:
These samples were collected and analyzed as part of an effort to map, quantitative survey, and sample seafloor benthic communities, associated sediment infauna, and motile organisms near seeps; characterize the physics and chemistry of sediments at seep locations and in the farfield; and geochronologic studies of authigenic carbonates to constrain the timing of methane seepage events as part of the CaMMeRA (Cascadia Margin Methane Research Action) project.
Supplemental_Information:
Additional information about the field activities from which these data were derived is available online at: http://cmgds.marine.usgs.gov/fan_info.php?fan=2019-619-FA Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
Time_Period_of_Content:
Time_Period_Information:
Range_of_Dates/Times:
Beginning_Date: 20190613
Ending_Date: 20190702
Currentness_Reference: Ground condition at time data were collected.
Status:
Progress: Complete
Maintenance_and_Update_Frequency: None planned
Spatial_Domain:
Bounding_Coordinates:
West_Bounding_Coordinate: -125.1778873
East_Bounding_Coordinate: -124.6393318
North_Bounding_Coordinate: 46.9602985
South_Bounding_Coordinate: 43.0138828
Keywords:
Theme:
Theme_Keyword_Thesaurus: ISO 19115 Topic Category
Theme_Keyword: oceans
Theme_Keyword: environment
Theme_Keyword: geoscientificInformation
Theme:
Theme_Keyword_Thesaurus: USGS Thesaurus
Theme_Keyword: gas hydrate resources
Theme_Keyword: geochemistry
Theme_Keyword: light stable isotope analysis
Theme_Keyword: chemical analysis
Theme:
Theme_Keyword_Thesaurus: Marine Realms Information Bank (MRIB) keywords
Theme_Keyword: sediment geochemistry
Theme_Keyword: push coring
Theme:
Theme_Keyword_Thesaurus: None
Theme_Keyword: U.S. Geological Survey
Theme_Keyword: USGS
Theme_Keyword: Coastal and Marine Hazards and Resources Program
Theme_Keyword: CMHRP
Theme_Keyword: Pacific Coastal and Marine Science Center
Theme_Keyword: PCMSC
Theme:
Theme_Keyword_Thesaurus: USGS Metadata Identifier
Theme_Keyword: USGS:669c1ff9d34e9ac16e169dc5
Place:
Place_Keyword_Thesaurus: Geographic Names Information System (GNIS)
Place_Keyword: Pacific Ocean
Place_Keyword: Coquille
Place:
Place_Keyword_Thesaurus: NGA GEOnet Names Server (GNS)
Place_Keyword: Heceta Bank
Place_Keyword: Nehalem Bank
Place_Keyword: Grays Canyon
Place_Keyword: Astoria Canyon
Place_Keyword: McArthur Escarpment
Access_Constraints: No access constraints
Use_Constraints:
USGS-authored or produced data and information are in the public domain from the U.S. Government and are freely redistributable with proper metadata and source attribution. Please recognize and acknowledge the U.S. Geological Survey, and the Schmidt Ocean Institute (SOI) as the originators of the dataset and in products derived from these data.
Point_of_Contact:
Contact_Information:
Contact_Organization_Primary:
Contact_Organization:
U.S. Geological Survey, Pacific Coastal and Marine Science Center
Contact_Person: PCMSC Science Data Coordinator
Contact_Address:
Address_Type: mailing and physical
Address: 2885 Mission Street
City: Santa Cruz
State_or_Province: CA
Postal_Code: 95060
Contact_Voice_Telephone: 831-427-4747
Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov
Data_Set_Credit:
Roberto Gwiazda (Monterey Bay Aquarium Research Institute), Susan Pit (University of California at Santa Cruz), Jennifer O’keefe Suttles (USGS), Ken Marchus (University of California at Santa Barbara), Colin Carney (University of California at Santa Cruz)
Native_Data_Set_Environment: Mac OS 11.4, Microsoft Excel 16.52 for Mac.
Cross_Reference:
Citation_Information:
Originator: J.D. Cline
Publication_Date: 1969
Title:
Spectrophotometric determination of hydrogen sulfide in natural waters
Other_Citation_Details:
Cline, J.D., 1969, Spectrophotometric determination of hydrogen sulfide in natural waters: Limnology and Oceanography, v. 14(3), p. 454-458.
Online_Linkage: https://doi.org/10.4319/lo.1969.14.3.0454
Cross_Reference:
Citation_Information:
Originator: B.K. Reese
Originator: D.W. Finneran
Originator: H.J Mills
Originator: M.X. Zhu
Originator: J.W. Morse
Publication_Date: 2011
Title:
Examination and refinement of the determination of aqueous hydrogen sulfide by the methylene blue method
Other_Citation_Details:
Reese, B.K., Finneran, D.W., Mills, H.J., Zhu, M.X., and Morese, J.W., 2011, Examination and refinement of the determination of aqueous hydrogen sulfide by the methylene blue method: Aquatic Geochemistry, v. 17, 567-582.
Online_Linkage: https://doi.org/10.1007/s10498-011-9128-1
Data_Quality_Information:
Attribute_Accuracy:
Attribute_Accuracy_Report: All geochemistry data were calibrated against known standards
Logical_Consistency_Report: No formal logical accuracy tests were conducted.
Completeness_Report:
Dataset is considered complete for the information presented, as described in the abstract. Users are advised to read the metadata for each part of this data release carefully for additional details. Dataset is considered complete for the information presented, as described in the abstract. Users are advised to read the metadata for each part of this data release carefully for additional details.
Positional_Accuracy:
Horizontal_Positional_Accuracy:
Horizontal_Positional_Accuracy_Report:
A formal accuracy assessment of the horizontal positional information in the data set has not been conducted. The horizontal accuracy is based on ship’s position using the navigations system; Global Navigation Satellite System (GNSS) called CNAV with an accuracy of 1 m.
Vertical_Positional_Accuracy:
Vertical_Positional_Accuracy_Report:
A formal accuracy assessment of the vertical positional information in the data set has not been conducted. Depth was determined using a Valeport minilPS depth sensor with a stated accuracy of 0.01 percent.
Lineage:
Source_Information:
Source_Citation:
Citation_Information:
Originator:
University of California at Santa Barbara, Marine Science Institute
Publication_Date: 2019
Title: Pore fluid nutrient analysis
Online_Linkage: http://msi.ucsb.edu/facilities-services/analytical-lab/about
Type_of_Source_Media: pore fluid lab samples
Source_Time_Period_of_Content:
Time_Period_Information:
Single_Date/Time:
Calendar_Date: 20191101
Source_Currentness_Reference: Date when lab analyses were completed
Source_Citation_Abbreviation: nutrient analysis
Source_Contribution:
Flow injection analysis for dissolved nutrient (nitrate, ammonia, phosphate, and silicate) concentrations.
Source_Information:
Source_Citation:
Citation_Information:
Originator:
University of California at Santa Cruz, Stable Isotope Laboratory
Publication_Date: 2021
Title: Pore fluid isotope analysis
Online_Linkage: https://isotope.ucsc.edu
Type_of_Source_Media: pore fluid lab samples
Source_Time_Period_of_Content:
Time_Period_Information:
Single_Date/Time:
Calendar_Date: 20210811
Source_Currentness_Reference: Date when lab analyses were completed
Source_Citation_Abbreviation: Oxygen (delta-O-18) and Hydrogen (delta-D) analysis of water
Source_Contribution:
A Picarro L2130-i isotope analyzer was used to determine pore fluid stable istopes of oxygen and hydrogen in water.
Source_Information:
Source_Citation:
Citation_Information:
Originator:
U.S. Geological Survey, Woods Hole Coastal and Marine Science Center
Publication_Date: 2019
Title: pore fluid sulfide analysis
Online_Linkage:
Type_of_Source_Media: pore fluid lab samples
Source_Time_Period_of_Content:
Time_Period_Information:
Single_Date/Time:
Calendar_Date: 20191211
Source_Currentness_Reference: Date when lab analyses were completed
Source_Citation_Abbreviation: sulfide
Source_Contribution:
Sulfide samples were analyzed spectrophotometrically following the methylene blue method (Cline SiL 1969; Reese and others, 2011) using a Thermo Scientific GENESYS 20 spectrophotometer (1 cm cell, 670 nanometer wavelength). The detection limit was determined as 2 times the concentration of the reagent blank (Reese and others 2011) or LOD =1 micromolar. Quality assurance included replicate analysis of prepared standards and field samples. Average coefficient of variation of replicates for this sample set was less than 1 percent.
Source_Information:
Source_Citation:
Citation_Information:
Originator: Monterey Bay Aquarium Research Institute (MBARI)
Publication_Date: 2019
Title: Pore fluid anion analysis
Type_of_Source_Media: Pore fluid lab samples
Source_Time_Period_of_Content:
Time_Period_Information:
Single_Date/Time:
Calendar_Date: 20190905
Source_Currentness_Reference: Date when lab analyses were completed
Source_Citation_Abbreviation: anions (sulfate and chloride)
Source_Contribution:
Dissolved anion concentrations, chloride (Cl-) and sulfate (SO42-) were analyzed using a DX-120 ion chromatograph ion chromatograph at Monterey Bay Aquarium Research Institute (MBARI). Pore water samples were filtered through 0.22 micron filters, diluted 1:100 with milli-Q water, and injected into a Dionex DX-120 ion chromatograph. Bracketing standards were run every five samples. Long-term reproducibility of Cl- and SO42-concentration measurements is 3.2 percent (2 sigma).
Process_Step:
Process_Description:
Sediment push cores were collected using the remotely operated vehicle (ROV) SuBastian (Schmidt Ocean Institute) and pore fluids were extracted using Rhizon samplers (0.15-micron pore size). Pore fluid samples were analyzed by several different labs (see Sources) for different variables. Data from all lab analyses were combined into a single document. -9999 cell value indicates no data (for example, where water sample was not analyzed for a particular variable given sample volume limitations).
Source_Used_Citation_Abbreviation: nutrient analysis
Source_Used_Citation_Abbreviation: anions
Source_Used_Citation_Abbreviation: sulfide
Source_Used_Citation_Abbreviation: Oxygen (delta-O-18) and Hydrogen (delta-D)
Process_Date: 2021
Source_Produced_Citation_Abbreviation: lab data
Process_Step:
Process_Description:
Sediment Pore fluid data were combined into a single document (FK109612_Porefluid_data.csv).
Source_Used_Citation_Abbreviation: lab data
Process_Date: 2021
Spatial_Data_Organization_Information:
Direct_Spatial_Reference_Method: Point
Point_and_Vector_Object_Information:
SDTS_Terms_Description:
SDTS_Point_and_Vector_Object_Type: Point
Point_and_Vector_Object_Count: 216
Spatial_Reference_Information:
Horizontal_Coordinate_System_Definition:
Geographic:
Latitude_Resolution: 0.0000001
Longitude_Resolution: 0.0000001
Geographic_Coordinate_Units: Decimal degrees
Geodetic_Model:
Horizontal_Datum_Name: D_WGS_1984
Ellipsoid_Name: D_WGS_1984
Semi-major_Axis: 6378137.000000
Denominator_of_Flattening_Ratio: 298.257224
Entity_and_Attribute_Information:
Detailed_Description:
Entity_Type:
Entity_Type_Label:
A comma-separated text file with the first line being a header line.
Entity_Type_Definition:
Output from chemical analysis of pore fluid samples collected from push cores
Entity_Type_Definition_Source: Producer defined.
Attribute:
Attribute_Label: Station
Attribute_Definition:
Name of ROV station which samples and measurements were collected based on cruise (FK190612=Falkor and cruise start date (190612) and consecutive ROV SuBastian dive number (for example, S257).
Attribute_Definition_Source: Producer defined
Attribute_Domain_Values:
Unrepresentable_Domain: List of station names
Attribute:
Attribute_Label: Date
Attribute_Definition: Sample collection date
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 2019-06-13
Range_Domain_Maximum: 2019-07-02
Attribute_Units_of_Measure: YYYY-MM-DD
Attribute:
Attribute_Label: Site ID
Attribute_Definition:
General site sample was collected based on site abbreviation (AC=Astoria Canyon; Grays=Grays Canyon; Heceta=Heceta Bank; Coquille; Nehalem; McArthur) and estimate water depth in m (for example, 550 m).
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Unrepresentable_Domain: List of site IDs
Attribute:
Attribute_Label: Cruise Sample ID
Attribute_Definition:
Unique cruise sample ID based on ROV SuBastian dive number (for example, S257) and consecutive sample number (for example, 007).
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Unrepresentable_Domain: List of cruise sample IDs
Attribute:
Attribute_Label: Latitude
Attribute_Definition: Latitude of sample location
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 43.0138828
Range_Domain_Maximum: 46.9602985
Attribute_Units_of_Measure: decimal degrees
Attribute_Measurement_Resolution: 0.0000001
Attribute:
Attribute_Label: Longitude
Attribute_Definition: Longitude of sample location
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: -125.1778873
Range_Domain_Maximum: -124.6393318
Attribute_Units_of_Measure: decimal degrees
Attribute_Measurement_Resolution: 0.000001
Attribute:
Attribute_Label: Depth
Attribute_Definition: Depth from the surface
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 184.726
Range_Domain_Maximum: 1352.950
Attribute_Units_of_Measure: meters
Attribute_Measurement_Resolution: 0.001
Attribute:
Attribute_Label: Push core number
Attribute_Definition: Number of push core
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 3
Range_Domain_Maximum: 32
Attribute_Units_of_Measure: unitless
Attribute_Measurement_Resolution: 1
Attribute:
Attribute_Label: Core depth
Attribute_Definition: Vertical depth in push core from top of sediment.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.0
Range_Domain_Maximum: 20.5
Attribute_Units_of_Measure: cm
Attribute_Measurement_Resolution: 0.1
Attribute:
Attribute_Label: Chloride
Attribute_Definition:
Pore fluid chloride concentration. Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 499.83
Range_Domain_Maximum: 580.71
Attribute_Units_of_Measure: millimolar
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Sulfate
Attribute_Definition:
Pore fluid sulfate concentration. Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.75
Range_Domain_Maximum: 41.05
Attribute_Units_of_Measure: millimolar
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Sulfide
Attribute_Definition:
Pore fluid sulfide concentration with dilution Factor due to 0.5mL Zinc Acetate addition. Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.0009
Range_Domain_Maximum: 0.1218
Attribute_Units_of_Measure: millimolar
Attribute_Measurement_Resolution: 0.0001
Attribute:
Attribute_Label: delta-O-18
Attribute_Definition:
delta-O-18 is a measure of the ratio of stable isotopes Oxygen-18:Oxygen-16 in water, reported in parts per thousand (per mil). Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: -1.18
Range_Domain_Maximum: 1.82
Attribute_Units_of_Measure: per mil
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: delta-D
Attribute_Definition:
delta-D is a measure of the ratio of stable isotopes Hydrogen (deuterium)-2:Hydrogen-1 in water, reported in parts per thousand (per mil). Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: Producer defined.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: -2.20
Range_Domain_Maximum: 7.67
Attribute_Units_of_Measure: per mil
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: phosphate
Attribute_Definition:
Dissolved inorganic phosphate concentration. Values of -9999 indicate the parameter was not measured.
Attribute_Definition_Source: standard reporting value in inorganic chemistry
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.04
Range_Domain_Maximum: 135.68
Attribute_Units_of_Measure: micromole per liter of seawater
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Silicate
Attribute_Definition:
Dissolved inorganic silicate concentration. Values of -9999 indicate the parameter was not measured
Attribute_Definition_Source: standard reporting value in inorganic chemistry
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.14
Range_Domain_Maximum: 628.04
Attribute_Units_of_Measure: micromole per liter of seawater
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Nitrite
Attribute_Definition:
Dissolved inorganic nitrite concentration. Values of -9999 indicate the parameter was not measured
Attribute_Definition_Source: standard reporting value in inorganic chemistry
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.02
Range_Domain_Maximum: 13.46
Attribute_Units_of_Measure: micromole per liter of seawater
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Nitrate and Nitrite
Attribute_Definition:
Dissolved inorganic nitrate and nitrite concentration. Values of -9999 indicate the parameter was not measured
Attribute_Definition_Source: standard reporting value in inorganic chemistry
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0.08
Range_Domain_Maximum: 39.42
Attribute_Units_of_Measure: micromole per liter of seawater
Attribute_Measurement_Resolution: 0.01
Attribute:
Attribute_Label: Ammonia
Attribute_Definition:
Dissolved inorganic ammonia concentration. Values of -9999 indicate the parameter was not measured
Attribute_Definition_Source: standard reporting value in inorganic chemistry.
Attribute_Domain_Values:
Range_Domain:
Range_Domain_Minimum: 0. 19
Range_Domain_Maximum: 494.33
Attribute_Units_of_Measure: micromole per liter of seawater
Attribute_Measurement_Resolution: 0.01
Overview_Description:
Entity_and_Attribute_Overview:
The first line of the comma-separated text file is a header line.
Entity_and_Attribute_Detail_Citation: U.S. Geological Survey
Distribution_Information:
Distributor:
Contact_Information:
Contact_Organization_Primary:
Contact_Organization: U.S. Geological Survey - ScienceBase
Contact_Address:
Address_Type: mailing and physical
Address: Denver Federal Center, Building 810, Mail Stop 302
City: Denver
State_or_Province: CO
Postal_Code: 80225
Contact_Voice_Telephone: 1-888-275-8747
Contact_Electronic_Mail_Address: sciencebase@usgs.gov
Resource_Description:
These data are available in a comma-delimited text file (FK190612_Porefluid_data.csv) which contains seawater carbonate analysis and CTD data for all collected water samples.
Distribution_Liability:
Unless otherwise stated, all data, metadata and related materials are considered to satisfy the quality standards relative to the purpose for which the data were collected. Although these data and associated metadata have been reviewed for accuracy and completeness and approved for release by the U.S. Geological Survey (USGS), no warranty expressed or implied is made regarding the display or utility of the data on any other system or for general or scientific purposes, nor shall the act of distribution constitute any such warranty.
Standard_Order_Process:
Digital_Form:
Digital_Transfer_Information:
Format_Name: comma-separated text
Format_Version_Number: 16.52
Format_Information_Content: comma-delimited text
File_Decompression_Technique: none
Transfer_Size: 0.05618
Digital_Transfer_Option:
Online_Option:
Computer_Contact_Information: Access_Instructions:
Data can be downloaded using the Network_Resource_Name links. The first link is a direct link to download the zipped file of data and metadata. The second link points to a landing page for the water parameter data and its metadata. The third link points to a landing page for the entire data release.
Fees: None.
Technical_Prerequisites: These data can be viewed with any text editor software.
Metadata_Reference_Information:
Metadata_Date: 20241121
Metadata_Contact:
Contact_Information:
Contact_Organization_Primary:
Contact_Organization:
U.S. Geological Survey, Pacific Coastal and Marine Science Center
Contact_Person: PCMSC Science Data Coordinator
Contact_Address:
Address_Type: mailing and physical
Address: 2885 Mission Street
City: Santa Cruz
State_or_Province: CA
Postal_Code: 95060
Contact_Voice_Telephone: 831-427-4747
Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov
Metadata_Standard_Name: Content Standard for Digital Geospatial Metadata
Metadata_Standard_Version: FGDC-STD-001-1998

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