Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater

Metadata also available as - [Questions & Answers] - [Parseable text] - [XML]

Metadata:

Identification_Information
Data_Quality_Information
Entity_and_Attribute_Information
Distribution_Information
Metadata_Reference_Information

Identification_Information:

Citation:

Citation_Information:

Originator: Amy Gartman
Originator: Samantha P. Whisman
Originator: James R. Hein
Publication_Date: 20201103
Title:

Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater

Geospatial_Data_Presentation_Form: comma-delimited text
Series_Information:

Series_Name: data release
Issue_Identification: DOI:10.5066/P9FZ16VG

Publication_Information:

Publication_Place:

Pacific Coastal and Marine Science Center, Santa Cruz, California

Publisher: U.S. Geological Survey

Online_Linkage: https://doi.org/10.5066/P9FZ16VG
Online_Linkage:

https://www.sciencebase.gov/catalog/item/5f86121e82cebef40f14c726

Description:

Abstract:

This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals.
These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste: ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00177, where they are also presented as Supplemental Table 1.

Purpose:

Data were used to determine the rate and process of sphalerite and ZnS oxidation in seawater, coupled to covellite.

Time_Period_of_Content:

Time_Period_Information:

Range_of_Dates/Times:

Beginning_Date: 20160101
Ending_Date: 20200815

Currentness_Reference: ground condition at time data were collected

Status:

Progress: Complete
Maintenance_and_Update_Frequency: None planned

Spatial_Domain:

Bounding_Coordinates:

West_Bounding_Coordinate: -180
East_Bounding_Coordinate: 180
North_Bounding_Coordinate: 90
South_Bounding_Coordinate: -90

Keywords:

Theme:

Theme_Keyword_Thesaurus: ISO 19115 Topic Category
Theme_Keyword: oceans
Theme_Keyword: geoscientificinformation
Theme_Keyword: economy

Theme:

Theme_Keyword_Thesaurus: Data Categories for Marine Planning
Theme_Keyword: Nonliving Resources

Theme:

Theme_Keyword_Thesaurus: USGS Thesaurus
Theme_Keyword: chemical analysis
Theme_Keyword: geochemistry
Theme_Keyword: metallic mineral resources

Theme:

Theme_Keyword_Thesaurus: Marine Realms Information Bank (MRIB) keywords
Theme_Keyword: chemical analysis
Theme_Keyword: mineral resources

Theme:

Theme_Keyword_Thesaurus: None
Theme_Keyword: U.S. Geological Survey
Theme_Keyword: USGS
Theme_Keyword: Coastal and Marine Hazards and Resources Program
Theme_Keyword: CMHRP
Theme_Keyword: Pacific Coastal and Marine Science Center
Theme_Keyword: PCMSC
Theme_Keyword: Marine Minerals

Theme:

Theme_Keyword_Thesaurus: USGS Metadata Identifier
Theme_Keyword: USGS:5f86121e82cebef40f14c726

Access_Constraints: None
Use_Constraints:

USGS-authored or produced data and information are in the public domain from the U.S. Government and are freely redistributable with proper metadata and source attribution. Please recognize and acknowledge the U.S. Geological Survey as the originator(s) of the dataset and in products derived from these data.

Point_of_Contact:

Contact_Information:

Contact_Organization_Primary:

Contact_Organization:

U.S. Geological Survey, Pacific Coastal and Marine Science Center

Contact_Person: PCMSC Science Data Coordinator

Contact_Address:

Address_Type: mailing and physical
Address: 2885 Mission Street
City: Santa Cruz
State_or_Province: CA
Postal_Code: 95060

Contact_Voice_Telephone: 831-460-7562
Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov

Native_Data_Set_Environment:

This data were created using a variety of standard electrochemical geochemical techniques.

Cross_Reference:

Citation_Information:

Originator: Amy Gartman
Originator: Samantha P. Whisman
Originator: James R. Hein
Publication_Date: 2020
Title:

Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste

Other_Citation_Details:

Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor massive sulfide deposits and mine waste: ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00177

Online_Linkage: https://doi.org/10.1021/acsearthspacechem.0c00177

Cross_Reference:

Citation_Information:

Originator: Anna Kocyla
Originator: Adam Pomorski
Originator: Artur Krezel
Publication_Date: 2017
Title:

Molar absorption coefficients and stability constants of Zincon metal complexes for determination of metal ions and bioinorganic applications

Other_Citation_Details:

Kocyla, A., Pomorski, A., and Krezel, A., 2017, Molar absorption coefficients and stability constants of Zincon metal complexes for determination of metal ions and bioinorganic applications: J. Inorg. Biochem., v. 176, p. 53-65

Online_Linkage: https://doi.org/10.1016/j.jinorgbio.2017.08.006

Data_Quality_Information:

Attribute_Accuracy:

Attribute_Accuracy_Report: Data may be considered accurate within 10 percent.

Logical_Consistency_Report:

Oxygen values are always below saturation. Time progresses linearly.

Completeness_Report: Data were included where measured.
Positional_Accuracy:

Horizontal_Positional_Accuracy:

Horizontal_Positional_Accuracy_Report: no positional information in are included in the data

Lineage:

Process_Step:

Process_Description:

Results from the all lab analyses were combined into a comma-delimited text document. See accompanying manuscript for sample-processing details.

Process_Date: 20200815
Process_Contact:

Contact_Information:

Contact_Person_Primary:

Contact_Person: Amy Gartman
Contact_Organization: U.S. Geological Survey

Contact_Position: Research Oceanographer
Contact_Address:

Address_Type: mailing and physical
Address: 2885 Mission St
City: Santa Cruz
State_or_Province: CA
Postal_Code: 95060

Contact_Voice_Telephone: 831-460-7562
Contact_Electronic_Mail_Address: agartman@usgs.gov

Entity_and_Attribute_Information:

Detailed_Description:

Entity_Type:

Entity_Type_Label: Attribute table
Entity_Type_Definition:

Table containing attribute information associated with the dataset

Entity_Type_Definition_Source: Producer defined

Attribute:

Attribute_Label: Trial
Attribute_Definition: Number of trial
Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Unrepresentable_Domain: trials sequentially numbered

Attribute:

Attribute_Label: Zn_added
Attribute_Definition: concentration of zinc added at the beginning of each trial
Attribute_Definition_Source: Producer defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 2.05 x 10^-4
Range_Domain_Maximum: 7.45 x 10^-3
Attribute_Units_of_Measure: moles per liter

Attribute:

Attribute_Label: Condition
Attribute_Definition: Description of conditions under which experiment was conducted
Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Unrepresentable_Domain:

specific to each trial; see details in Gartman and others (2020)

Attribute:

Attribute_Label: Temperature
Attribute_Definition: temperature at which experiment was conducted
Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 22
Range_Domain_Maximum: 62
Attribute_Units_of_Measure: degrees Celsius

Attribute:

Attribute_Label: Time
Attribute_Definition: time elapsed from onset of experiment to time of measurement
Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 0
Range_Domain_Maximum: 123.75
Attribute_Units_of_Measure: days

Attribute:

Attribute_Label: Zn_measured
Attribute_Definition:

concentration of zinc measured; -9999 indicates no data, -8888 indicates the value was below the detection limit

Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 1.47 x 10^-7
Range_Domain_Maximum: 1.24 x 10^-4
Attribute_Units_of_Measure: moles per liter

Attribute:

Attribute_Label: pH
Attribute_Definition: pH of the solution; -9999 indicates no data
Attribute_Definition_Source: producer defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 7.26
Range_Domain_Maximum: 8.52
Attribute_Units_of_Measure: log scale

Attribute:

Attribute_Label: O2
Attribute_Definition: dissolved oxygen in the solution; -9999 indicates no data
Attribute_Definition_Source: Produce defined
Attribute_Domain_Values:

Range_Domain:

Range_Domain_Minimum: 3.71 x 10^-5
Range_Domain_Maximum: 2.50 x 10^-4
Attribute_Units_of_Measure: moles per liter

Overview_Description:

Entity_and_Attribute_Overview: The first line of the csv file is a header line.
Entity_and_Attribute_Detail_Citation: U.S. Geological Survey

Distribution_Information:

Distributor:

Contact_Information:

Contact_Organization_Primary:

Contact_Organization: U.S. Geological Survey - ScienceBase

Contact_Address:

Address_Type: mailing and physical
Address: Denver Federal Center, Building 810, Mail Stop 302
City: Denver
State_or_Province: CO
Postal_Code: 80225

Contact_Voice_Telephone: 1-888-275-8747
Contact_Electronic_Mail_Address: sciencebase@usgs.gov

Resource_Description:

These data are available in csv format contained in a single file.

Distribution_Liability:

Unless otherwise stated, all data, metadata and related materials are considered to satisfy the quality standards relative to the purpose for which the data were collected. Although these data and associated metadata have been reviewed for accuracy and completeness and approved for release by the U.S. Geological Survey (USGS), no warranty expressed or implied is made regarding the display or utility of the data on any other system or for general or scientific purposes, nor shall the act of distribution constitute any such warranty.

Standard_Order_Process:

Digital_Form:

Digital_Transfer_Information:

Format_Name: comma-delimited text
Format_Version_Number: Microsoft Excel 16.16.17 for Mac
Format_Information_Content: csv
File_Decompression_Technique: No compression applied
Transfer_Size: 0.035

Digital_Transfer_Option:

Online_Option:

Computer_Contact_Information:

Network_Address:

Network_Resource_Name:

https://www.sciencebase.gov/catalog/file/get/5f86121e82cebef40f14c726

Network_Resource_Name: https://doi.org/10.5066/P9FZ16VG

Access_Instructions:

Data can be downloaded using the Network_Resource_Name links. The first link is a direct link to download the zipped file of data and metadata. The second link points to a landing page with metadata and data

Fees: None.

Technical_Prerequisites: These data can be viewed with any text reader software.

Metadata_Reference_Information:

Metadata_Date: 20201103
Metadata_Contact:

Contact_Information:

Contact_Organization_Primary:

Contact_Organization:

U.S. Geological Survey, Pacific Coastal and Marine Science Center

Contact_Person: PCMSC Science Data Coordinator

Contact_Address:

Address_Type: mailing and physical
Address: 2885 Mission Street
City: Santa Cruz
State_or_Province: CA
Postal_Code: 95060

Contact_Voice_Telephone: 831-427-4747
Contact_Electronic_Mail_Address: pcmsc_data@usgs.gov

Metadata_Standard_Name: Content Standard for Digital Geospatial Metadata
Metadata_Standard_Version: FGDC-STD-001-1998

This page is <https://cmgds.marine.usgs.gov/catalog/pcmsc/DataReleases/ScienceBase/DR_P9FZ16VG/Zn_O2_pH_metadata.html>